ball mill processs

ball milling | material milling, jet milling | aveka

Ball milling is a size reduction technique that uses media in a rotating cylindrical chamber to mill materials to a fine powder. As the chamber rotates, the media is lifted up on the rising side and then cascades down from near the top of the chamber. With this motion, the particles in between the media and chamber walls are reduced in size by both impact and abrasion. In ball milling, the desired particle size is achieved by controlling the time, applied energy, and the size and density of the grinding media. The optimal milling occurs at a critical speed. Ball mills can operate in either a wet or dry state. While milling without any added liquid is commonplace, adding water or other liquids can produce the finest particles and provide a ready-to-use dispersion at the same time.

Grinding media comes in many shapes and types with each having its own specific properties and advantages. Key properties of grinding media include composition, hardness, size and density. Some common types include alumina, stainless steel, yttria stabilized zirconia and sand. Ball milling will result in a ball curve particle size distribution with one or more peaks. Screening may be required to remove over or undersized materials.

ball mills

In all ore dressing and milling Operations, including flotation, cyanidation, gravity concentration, and amalgamation, the Working Principle is to crush and grind, often with rob mill & ball mills, the ore in order to liberate the minerals. In the chemical and process industries, grinding is an important step in preparing raw materials for subsequent treatment.In present day practice, ore is reduced to a size many times finer than can be obtained with crushers. Over a period of many years various fine grinding machines have been developed and used, but the ball mill has become standard due to its simplicity and low operating cost.

A ball millefficiently operated performs a wide variety of services. In small milling plants, where simplicity is most essential, it is not economical to use more than single stage crushing, because the Steel-Head Ball or Rod Mill will take up to 2 feed and grind it to the desired fineness. In larger plants where several stages of coarse and fine crushing are used, it is customary to crush from 1/2 to as fine as 8 mesh.

Many grinding circuits necessitate regrinding of concentrates or middling products to extremely fine sizes to liberate the closely associated minerals from each other. In these cases, the feed to the ball mill may be from 10 to 100 mesh or even finer.

Where the finished product does not have to be uniform, a ball mill may be operated in open circuit, but where the finished product must be uniform it is essential that the grinding mill be used in closed circuit with a screen, if a coarse product is desired, and with a classifier if a fine product is required. In most cases it is desirable to operate the grinding mill in closed circuit with a screen or classifier as higher efficiency and capacity are obtained. Often a mill using steel rods as the grinding medium is recommended, where the product must have the minimum amount of fines (rods give a more nearly uniform product).

Often a problem requires some study to determine the economic fineness to which a product can or should be ground. In this case the 911Equipment Company offers its complete testing service so that accurate grinding mill size may be determined.

Until recently many operators have believed that one particular type of grinding mill had greater efficiency and resulting capacity than some other type. However, it is now commonly agreed and accepted that the work done by any ballmill depends directly upon the power input; the maximum power input into any ball or rod mill depends upon weight of grinding charge, mill speed, and liner design.

The apparent difference in capacities between grinding mills (listed as being the same size) is due to the fact that there is no uniform method of designating the size of a mill, for example: a 5 x 5 Ball Mill has a working diameter of 5 inside the liners and has 20 per cent more capacity than all other ball mills designated as 5 x 5 where the shell is 5 inside diameter and the working diameter is only 48 with the liners in place.

Ball-Rod Mills, based on 4 liners and capacity varying as 2.6 power of mill diameter, on the 5 size give 20 per cent increased capacity; on the 4 size, 25 per cent; and on the 3 size, 28 per cent. This fact should be carefully kept in mind when determining the capacity of a Steel- Head Ball-Rod Mill, as this unit can carry a greater ball or rod charge and has potentially higher capacity in a given size when the full ball or rod charge is carried.

A mill shorter in length may be used if the grinding problem indicates a definite power input. This allows the alternative of greater capacity at a later date or a considerable saving in first cost with a shorter mill, if reserve capacity is not desired. The capacities of Ball-Rod Mills are considerably higher than many other types because the diameters are measured inside the liners.

The correct grinding mill depends so much upon the particular ore being treated and the product desired, that a mill must have maximum flexibility in length, type of grinding medium, type of discharge, and speed.With the Ball-Rod Mill it is possible to build this unit in exact accordance with your requirements, as illustrated.

To best serve your needs, the Trunnion can be furnished with small (standard), medium, or large diameter opening for each type of discharge. The sketch shows diagrammatic arrangements of the four different types of discharge for each size of trunnion opening, and peripheral discharge is described later.

Ball-Rod Mills of the grate discharge type are made by adding the improved type of grates to a standard Ball-Rod Mill. These grates are bolted to the discharge head in much the same manner as the standard headliners.

The grates are of alloy steel and are cast integral with the lifter bars which are essential to the efficient operation of this type of ball or rod mill. These lifter bars have a similar action to a pump:i. e., in lifting the product so as to discharge quickly through the mill trunnion.

These Discharge Grates also incorporate as an integral part, a liner between the lifters and steel head of the ball mill to prevent wear of the mill head. By combining these parts into a single casting, repairs and maintenance are greatly simplified. The center of the grate discharge end of this mill is open to permit adding of balls or for adding water to the mill through the discharge end.

Instead of being constructed of bars cast into a frame, Grates are cast entire and have cored holes which widen toward the outside of the mill similar to the taper in grizzly bars. The grate type discharge is illustrated.

The peripheral discharge type of Ball-Rod Mill is a modification of the grate type, and is recommended where a free gravity discharge is desired. It is particularly applicable when production of too many fine particles is detrimental and a quick pass through the mill is desired, and for dry grinding.

The drawings show the arrangement of the peripheral discharge. The discharge consists of openings in the shell into which bushings with holes of the desired size are inserted. On the outside of the mill, flanges are used to attach a stationary discharge hopper to prevent pulp splash or too much dust.

The mill may be operated either as a peripheral discharge or a combination or peripheral and trunnion discharge unit, depending on the desired operating conditions. If at any time the peripheral discharge is undesirable, plugs inserted into the bushings will convert the mill to a trunnion discharge type mill.

Unless otherwise specified, a hard iron liner is furnished. This liner is made of the best grade white iron and is most serviceable for the smaller size mills where large balls are not used. Hard iron liners have a much lower first cost.

Electric steel, although more expensive than hard iron, has advantage of minimum breakage and allows final wear to thinner section. Steel liners are recommended when the mills are for export or where the source of liner replacement is at a considerable distance.

Molychrome steel has longer wearing qualities and greater strength than hard iron. Breakage is not so apt to occur during shipment, and any size ball can be charged into a mill equipped with molychrome liners.

Manganese liners for Ball-Rod Mills are the world famous AMSCO Brand, and are the best obtainable. The first cost is the highest, but in most cases the cost per ton of ore ground is the lowest. These liners contain 12 to 14% manganese.

The feed and discharge trunnions are provided with cast iron or white iron throat liners. As these parts are not subjected to impact and must only withstand abrasion, alloys are not commonly used but can be supplied.

Gears for Ball-Rod Mills drives are furnished as standard on the discharge end of the mill where they are out of the way of the classifier return, scoop feeder, or original feed. Due to convertible type construction the mills can be furnished with gears on the feed end. Gear drives are available in two alternative combinations, which are:

All pinions are properly bored, key-seated, and pressed onto the steel countershaft, which is oversize and properly keyseated for the pinion and drive pulleys or sheaves. The countershaft operates on high grade, heavy duty, nickel babbitt bearings.

Any type of drive can be furnished for Ball-Rod Mills in accordance with your requirements. Belt drives are available with pulleys either plain or equipped with friction clutch. Various V- Rope combinations can also be supplied.

The most economical drive to use up to 50 H. P., is a high starting torque motor connected to the pinion shaft by means of a flat or V-Rope drive. For larger size motors the wound rotor (slip ring) is recommended due to its low current requirement in starting up the ball mill.

Should you be operating your own power plant or have D. C. current, please specify so that there will be no confusion as to motor characteristics. If switches are to be supplied, exact voltage to be used should be given.

Even though many ores require fine grinding for maximum recovery, most ores liberate a large percentage of the minerals during the first pass through the grinding unit. Thus, if the free minerals can be immediately removed from the ball mill classifier circuit, there is little chance for overgrinding.

This is actually what has happened wherever Mineral Jigs or Unit Flotation Cells have been installed in the ball mill classifier circuit. With the installation of one or both of these machines between the ball mill and classifier, as high as 70 per cent of the free gold and sulphide minerals can be immediately removed, thus reducing grinding costs and improving over-all recovery. The advantage of this method lies in the fact that heavy and usually valuable minerals, which otherwise would be ground finer because of their faster settling in the classifier and consequent return to the grinding mill, are removed from the circuit as soon as freed. This applies particularly to gold and lead ores.

Ball-Rod Mills have heavy rolled steel plate shells which are arc welded inside and outside to the steel heads or to rolled steel flanges, depending upon the type of mill. The double welding not only gives increased structural strength, but eliminates any possibility of leakage.

Where a single or double flanged shell is used, the faces are accurately machined and drilled to template to insure perfect fit and alignment with the holes in the head. These flanges are machined with male and female joints which take the shearing stresses off the bolts.

The Ball-Rod Mill Heads are oversize in section, heavily ribbed and are cast from electric furnace steel which has a strength of approximately four times that of cast iron. The head and trunnion bearings are designed to support a mill with length double its diameter. This extra strength, besides eliminating the possibility of head breakage or other structural failure (either while in transit or while in service), imparts to Ball-Rod Mills a flexibility heretofore lacking in grinding mills. Also, for instance, if you have a 5 x 5 mill, you can add another 5 shell length and thus get double the original capacity; or any length required up to a maximum of 12 total length.

On Type A mills the steel heads are double welded to the rolled steel shell. On type B and other flanged type mills the heads are machined with male and female joints to match the shell flanges, thus taking the shearing stresses from the heavy machine bolts which connect the shell flanges to the heads.

The manhole cover is protected from wear by heavy liners. An extended lip is provided for loosening the door with a crow-bar, and lifting handles are also provided. The manhole door is furnished with suitable gaskets to prevent leakage.

The mill trunnions are carried on heavy babbitt bearings which provide ample surface to insure low bearing pressure. If at any time the normal length is doubled to obtain increased capacity, these large trunnion bearings will easily support the additional load. Trunnion bearings are of the rigid type, as the perfect alignment of the trunnion surface on Ball-Rod Mills eliminates any need for the more expensive self-aligning type of bearing.

The cap on the upper half of the trunnion bearing is provided with a shroud which extends over the drip flange of the trunnion and effectively prevents the entrance of dirt or grit. The bearing has a large space for wool waste and lubricant and this is easily accessible through a large opening which is covered to prevent dirt from getting into the bearing.Ball and socket bearings can be furnished.

Scoop Feeders for Ball-Rod Mills are made in various radius sizes. Standard scoops are made of cast iron and for the 3 size a 13 or 19 feeder is supplied, for the 4 size a 30 or 36, for the 5 a 36 or 42, and for the 6 a 42 or 48 feeder. Welded steel scoop feeders can, however, be supplied in any radius.

The correct size of feeder depends upon the size of the classifier, and the smallest feeder should be used which will permit gravity flow for closed circuit grinding between classifier and the ball or rod mill. All feeders are built with a removable wearing lip which can be easily replaced and are designed to give minimum scoop wear.

A combination drum and scoop feeder can be supplied if necessary. This feeder is made of heavy steel plate and strongly welded. These drum-scoop feeders are available in the same sizes as the cast iron feeders but can be built in any radius. Scoop liners can be furnished.

The trunnions on Ball-Rod Mills are flanged and carefully machined so that scoops are held in place by large machine bolts and not cap screws or stud bolts. The feed trunnion flange is machined with a shoulder for insuring a proper fit for the feed scoop, and the weight of the scoop is carried on this shoulder so that all strain is removed from the bolts which hold the scoop.

High carbon steel rods are recommended, hot rolled, hot sawed or sheared, to a length of 2 less than actual length of mill taken inside the liners. The initial rod charge is generally a mixture ranging from 1.5 to 3 in diameter. During operation, rod make-up is generally the maximum size. The weights per lineal foot of rods of various diameters are approximately: 1.5 to 6 lbs.; 2-10.7 lbs.; 2.5-16.7 lbs.; and 3-24 lbs.

Forged from the best high carbon manganese steel, they are of the finest quality which can be produced and give long, satisfactory service. Data on ball charges for Ball-Rod Mills are listed in Table 5. Further information regarding grinding balls is included in Table 6.

Rod Mills has a very define and narrow discharge product size range. Feeding a Rod Mill finer rocks will greatly impact its tonnage while not significantly affect its discharge product sizes. The 3.5 diameter rod of a mill, can only grind so fine.

Crushers are well understood by most. Rod and Ball Mills not so much however as their size reduction actions are hidden in the tube (mill). As for Rod Mills, the image above best expresses what is going on inside. As rocks is feed into the mill, they are crushed (pinched) by the weight of its 3.5 x 16 rods at one end while the smaller particles migrate towards the discharge end and get slightly abraded (as in a Ball Mill) on the way there.

We haveSmall Ball Mills for sale coming in at very good prices. These ball mills are relatively small, bearing mounted on a steel frame. All ball mills are sold with motor, gears, steel liners and optional grinding media charge/load.

Ball Mills or Rod Mills in a complete range of sizes up to 10 diameter x20 long, offer features of operation and convertibility to meet your exactneeds. They may be used for pulverizing and either wet or dry grindingsystems. Mills are available in both light-duty and heavy-duty constructionto meet your specific requirements.

All Mills feature electric cast steel heads and heavy rolled steelplate shells. Self-aligning main trunnion bearings on large mills are sealedand internally flood-lubricated. Replaceable mill trunnions. Pinion shaftbearings are self-aligning, roller bearing type, enclosed in dust-tightcarrier. Adjustable, single-unit soleplate under trunnion and drive pinionsfor perfect, permanent gear alignment.

Ball Mills can be supplied with either ceramic or rubber linings for wet or dry grinding, for continuous or batch type operation, in sizes from 15 x 21 to 8 x 12. High density ceramic linings of uniform hardness male possible thinner linings and greater and more effective grinding volume. Mills are shipped with liners installed.

Complete laboratory testing service, mill and air classifier engineering and proven equipment make possible a single source for your complete dry-grinding mill installation. Units available with air swept design and centrifugal classifiers or with elevators and mechanical type air classifiers. All sizes and capacities of units. Laboratory-size air classifier also available.

A special purpose batch mill designed especially for grinding and mixing involving acids and corrosive materials. No corners mean easy cleaning and choice of rubber or ceramic linings make it corrosion resistant. Shape of mill and ball segregation gives preferential grinding action for grinding and mixing of pigments and catalysts. Made in 2, 3 and 4 diameter grinding drums.

Nowadays grinding mills are almost extensively used for comminution of materials ranging from 5 mm to 40 mm (3/161 5/8) down to varying product sizes. They have vast applications within different branches of industry such as for example the ore dressing, cement, lime, porcelain and chemical industries and can be designed for continuous as well as batch grinding.

Ball mills can be used for coarse grinding as described for the rod mill. They will, however, in that application produce more fines and tramp oversize and will in any case necessitate installation of effective classification.If finer grinding is wanted two or three stage grinding is advisable as for instant primary rod mill with 75100 mm (34) rods, secondary ball mill with 2540 mm(11) balls and possibly tertiary ball mill with 20 mm () balls or cylpebs.To obtain a close size distribution in the fine range the specific surface of the grinding media should be as high as possible. Thus as small balls as possible should be used in each stage.

The principal field of rod mill usage is the preparation of products in the 5 mm0.4 mm (4 mesh to 35 mesh) range. It may sometimes be recommended also for finer grinding. Within these limits a rod mill is usually superior to and more efficient than a ball mill. The basic principle for rod grinding is reduction by line contact between rods extending the full length of the mill, resulting in selective grinding carried out on the largest particle sizes. This results in a minimum production of extreme fines or slimes and more effective grinding work as compared with a ball mill. One stage rod mill grinding is therefore suitable for preparation of feed to gravimetric ore dressing methods, certain flotation processes with slime problems and magnetic cobbing. Rod mills are frequently used as primary mills to produce suitable feed to the second grinding stage. Rod mills have usually a length/diameter ratio of at least 1.4.

Tube mills are in principle to be considered as ball mills, the basic difference being that the length/diameter ratio is greater (35). They are commonly used for surface cleaning or scrubbing action and fine grinding in open circuit.

In some cases it is suitable to use screened fractions of the material as grinding media. Such mills are usually called pebble mills, but the working principle is the same as for ball mills. As the power input is approximately directly proportional to the volume weight of the grinding media, the power input for pebble mills is correspondingly smaller than for a ball mill.

A dry process requires usually dry grinding. If the feed is wet and sticky, it is often necessary to lower the moisture content below 1 %. Grinding in front of wet processes can be done wet or dry. In dry grinding the energy consumption is higher, but the wear of linings and charge is less than for wet grinding, especially when treating highly abrasive and corrosive material. When comparing the economy of wet and dry grinding, the different costs for the entire process must be considered.

An increase in the mill speed will give a directly proportional increase in mill power but there seems to be a square proportional increase in the wear. Rod mills generally operate within the range of 6075 % of critical speed in order to avoid excessive wear and tangled rods. Ball and pebble mills are usually operated at 7085 % of critical speed. For dry grinding the speed is usually somewhat lower.

The mill lining can be made of rubber or different types of steel (manganese or Ni-hard) with liner types according to the customers requirements. For special applications we can also supply porcelain, basalt and other linings.

The mill power is approximately directly proportional to the charge volume within the normal range. When calculating a mill 40 % charge volume is generally used. In pebble and ball mills quite often charge volumes close to 50 % are used. In a pebble mill the pebble consumption ranges from 315 % and the charge has to be controlled automatically to maintain uniform power consumption.

In all cases the net energy consumption per ton (kWh/ton) must be known either from previous experience or laboratory tests before mill size can be determined. The required mill net power P kW ( = ton/hX kWh/ton) is obtained from

Trunnions of S.G. iron or steel castings with machined flange and bearing seat incl. device for dismantling the bearings. For smaller mills the heads and trunnions are sometimes made in grey cast iron.

The mills can be used either for dry or wet, rod or ball grinding. By using a separate attachment the discharge end can be changed so that the mills can be used for peripheral instead of overflow discharge.

ball mill maintenance & installation procedure

Am sure your BallMill is considered the finest possible grinding mill available. As such you will find it is designed and constructed according to heavy duty specifications. It is designed along sound engineering principles with quality workmanship and materials used in the construction of the component parts. YourBallMill reflects years of advancement in grinding principles, materials, and manufacturing techniques. It has been designed with both the operators and the erectors viewpoints in mind. Long uninterrupted performance can be expected from it if the instructions covering installation and maintenance of the mill are carried out. You may be familiar with installing mills of other designs and manufacture much lighter in construction. YourBallis heavy and rugged. It should, therefore, be treated accordingly with due respect for its heavier construction.

The purpose of this manual is to assist you in the proper installation and to acquaint you a bit further with the assembly and care of this equipment. We suggest that these instructions be read carefully and reviewed by everyone whenever involved in the actual installation and operation of the mill. In reading these general instructions, you may at times feel that they cover items which are elementary and perhaps not worthy of mention; however in studying hundreds of installations, it has been found that very often minor points are overlooked due to pressure being exerted by outside influences to get the job done in a hurry. The erection phase of this mill is actually no place to attempt cost savings by taking short cuts, or by-passing some of the work. A good installation will pay dividends for many years to come by reduced maintenance cost.With the modern practice of specialized skills and trades, there is often a line drawn between responsibilities of one crew of erectors and another. Actually the responsibility of installation does not cease with the completion of one phase nor does it begin with the starting of another. Perhaps a simple rule to adopt would be DO NOT TAKE ANYTHING FOR GRANTED. This policy of rechecking previously done work will help guarantee each step of the erection and it will carefully coordinate and tie it into subsequent erection work. To clarify or illustrate this point, take the example of concrete workers completing their job and turning it over to the machinist or millwright. The latter group should carefully check the foundation for soundness and correctness prior to starting their work.

Sound planning and good judgement will, to a great extent, be instrumental in avoiding many of the troublesome occurrences especially at the beginning of operations. While it is virtually impossible to anticipate every eventuality, nevertheless it is the intention of this manual to outline a general procedure to follow in erecting the mill, and at the same time, point out some of the pitfalls which should be avoided.

Before starting the erection of the mill, adequate handling facilities should be provided or made available, bearing in mind the weights and proportions of the various parts and sub-assemblies. This information can be ascertained from the drawings and shipping papers.

The gearing, bearings, and other machined surfaces have been coated with a protective compound, and should be cleaned thoroughly with a solvent, such as Chlorothene, (made by Dow Chemical). Judgement should be exercised as to the correct time and place for cleaning the various parts. Do not permit solvents, oil or grease to come in contact with the roughened top surfaces of the concrete foundation where grouting is to be applied; otherwise proper bonding will not result.

After cleaning the various parts, the gear and pinion teeth, trunnion journals and bearings, shafting and such, should be protected against rusting or pitting as well as against damage from falling objects or weld splatter. All burrs should be carefully removed by filing or honing.

Unless otherwise arranged for, the mill has been completely assembled in our shop. Before dismantling, the closely fitted parts were match marked, and it will greatly facilitate field assembly to adhere to these match marks.

The surfaces of all connecting joints or fits, such as shell and head flanges, trunnion flanges, trunnion liner and feeder connecting joints, should be coated with a NON-SETTING elastic compound, such as Quigley O-Seal, or Permatex to insure against leakage and to assist in drawing them up tight. DO NOT USE WHITE LEAD OR GREASE.

Parts which are affected by the hand of the mill are easily identified by referring to the parts list. In general they include the feeder, feed trunnion liner, discharge trunnion liner if it is equipped with a spiral, spiral type helical splitter, and in some cases the pan liners when they are of the spiral type. When both right and left hand mills are being assembled, it is imperative that these parts which involve hand be assembled in the correct mill.

Adequate foundations for any heavy equipment, and in particular grinding mills, are extremely important to assure proper operation. The foundation should preferably be in one piece, that is, with a reinforced slab footing (so called mat) extending under both trunnion bearing foundations as well as the pinion bearing foundation. If possible or practical, it should be extended to include also the motor and drive. With this design, in the event of some movement, the mill and foundation will tend to move as a unit. ANY SLIGHT SETTLING OF FOUNDATIONS WILL CAUSE BEARING AND GEAR MISALIGNMENT, resulting in excessive wear and higher maintenance costs. It has been found that concrete foundations on a weight basis should be at least 1 times the total weight of the grinding mill with its grinding media.

Allowable bearing pressure between concrete footings and the soil upon which the foundation rests should first be considered. The center of pressure must always pass through the center of the footing. Foundations subject to shock should be designed with less unit pressure than foundations for stationary loads. High moisture content in soils reduces the amount of allowable specific pressure that the ground can support. The following figures may be used for preliminary foundation calculations.

Portland cement mixed with sand and aggregate in the proper proportions has come to be standard practice in making concrete. For general reference cement is usually shipped in sacks containing one cubic foot of material. A barrel usually holds 4 cubic feet. Cement will deteriorate with age and will quickly absorb moisture so it should be stored in a dry place. For best results the sand and gravel used should be carefully cleaned free of humus, clay, vegetal matter, etc.

Concrete may be made up in different mixtures having different proportions of sand and aggregate. These are expressed in parts for example a 1:2:4 mixture indicates one bag of cement, 2 cubic feet of sand, and 4 cubic feet of gravel. We recommend a mixture of 1:2:3 for ball mill and rod mill foundations. The proper water to sand ratio should be carefully regulated since excess water increases the shrinkage in the concrete and lends to weaken it even more than a corresponding increase in the aggregate. Between 5 to 8 gallons of water to a sack of cement is usually recommended, the lower amount to be used where higher strength is required or where the concrete will be subject to severe weathering conditions.

Detailed dimensions for the concrete foundation are covered by the foundation plan drawing submitted separately. The drawing also carries special instructions as to the allowance for grouting, steel reinforcements, pier batter, foundation bolts and pipes. During concrete work, care should be taken to prevent concrete entering the pipes, surrounding the foundations bolts, which would limit the positioning of the bolts when erecting the various assemblies. Forms should be adequately constructed and reinforced to prevent swell, particularly where clearance is critical such as at the drive end where the gear should clear the trunnion bearing and pinion bearing piers.

For convenience in maintenance, the mill foundations should be equipped with jacking piers. These will allow the lifting of one end of the mill by use of jacks in the event maintenance must be carried out under these conditions.

Adequate foundations for any heavy equipment, and in particular Marcy grinding mills, are extremely important to assure proper operation of that equipment. Any slight settling of foundations will cause bearing and gear misalignment, resulting in excessive wear and higher maintenance costs. It has been found that concrete foundations on a weight basis should be approximately 1 times the total weight of the grinding mill with its grinding media.

Allowable bearing pressure between concrete footings and the soil upon which the foundation rests should first be considered. The center of pressure must always pass through the center of the footing. Foundations subject to shock should be designed with less unit pressures than foundations for stationary loads. High moisture content in soils reduces the amount of allowable pressure that that material can support. The following figures may be used for quick foundation calculations:

Portland cement mixed with sand and aggregate in the proper proportions has come to be standard practice in making concrete. For general reference cement is usually shipped in sacks containing one cubic foot of material. A barrel usually consists of 4 cubic feet. Cement will deteriorate with age and will quickly absorb moisture so it should be stored in a cool, dry place. The sand and gravel used should be carefully cleaned for best results to be sure of minimizing the amount of sedimentation in that material.

Concrete may be made up in different mixtures having different proportions of sand and aggregate. These are expressed in parts for example a 1:2:4 mixture indicates one bag of cement, 2 cubic feet of sand, and 4 cubic feet of gravel. We recommend a mixture of 1:2:3 for ball mill and rod mill foundations. The proper water to sand ratio should be carefully regulated since excess water will tend to weaken the concrete even more than corresponding variations in other material ratios. Between 5 to 8 gallons of water to a sack of cement is usually recommended, the lower amount to be used where higher strength is required or where the concrete will be subject to severe weathering conditions.

We recommend the use of a non-shrinking grout, and preferably of the pre-mixed type, such as Embeco, made by the Master Builders Company of Cleveland, Ohio. Thoroughly clean the top surfaces of the concrete piers, and comply with the instructions of the grouting supplier.

1. Establish vertical and horizontal centerline of mill and pinion shaftagainst the effects of this, we recommend that the trunnion bearing sole plate be crowned so as to be higher at the center line of the mill. This is done by using a higher shim at the center than at the endsand tightening the foundation bolts of both ends.

After all shimming is completed, the sole plate and bases should be grouted in position. Grouting should be well tamped and should completely fill the underside of the sole plate and bases. DO NOT REMOVE THE SHIMS AFTER OR DURING GROUTING. When the grout has hardened sufficiently it is advisable to paint the top surfaces of the concrete so as to protect it against disintegration due to the absorption of oil or grease.

If it is felt that sufficient accuracy in level between trunnion bearing piers cannot be maintained, we recommend that the grouting of the sole plate under the trunnion bearing opposite the gear end be delayed until after the mill is in place. In this way, the adjustment by shimming at this end can be made later to correct for any errors in elevation. Depending on local climatic conditions, two to seven days should he allowed for the grouting to dry and set, before painting or applying further loads to the piers.

Pinion bearings are provided of either the sleeve type or anti-friction type. Twin bearing construction may use either individual sole plates or a cast common sole plate. The unit with a common sole plate is completely assembled in our shop and is ready for installation. Normal inspection and cleaning procedure should be followed. Refer to the parts list for general assembly. These units are to be permanently grouted in position and, therefore, care should be taken to assure correct alignment.

The trunnion bearing assemblies can now be mounted on their sole plates. If the bearings are of the swivel type, a heavy industrial water-proof grease should be applied to the spherical surfaces of both the swivels and the bases. Move the trunnion bearings to their approximate position by adjustment of the set screws provided for this purpose.

In the case of ball mills, all internal wearing parts will pass through the manhole, whereas in the case of open end rod mills they will pass through the discharge trunnion opening. When lining the shell, start with the odd shaped pieces around the manhole opening if manholes are furnished. Rubber shell liner backing should be used with all cast type rod mills shell liners. If the shell liners are of the step type, they should be assembled with the thin portion, or toe, as the leading edge with respect to rotation of the mill.

Lorain liners for the shell are provided with special round head bolts, with a waterproof washer and nut. All other cast type liners for the head and shell are provided with oval head bolts with a cut washer and nuts. Except when water proof washers are used, it is advisable to wrap four or five turns of candle wicking around the shank of the bolt under the cut washer. Dip the candle wicking in white lead. All liner bolt threads should be dipped in graphite and oil before assembly. All liner bolt cuts should be firmly tightened by use of a pipe extension on a wrench, or better yet, by use of a torque wrench. The bolt heads should be driven firmly into the bolt holes with a hammer.

In order to minimise the effect of pulp race, we recommend that the spaces between the ends of the shell liners and the head liners or grates be filled with suitable packing. This packing may be in the form of rubber belting, hose, rope or wood.

If adequate overhead crane facilities are available, the heads can be assembled to the shell with the flange connecting bolts drawn tightly. Furthermore, the liners can be in place, as stated above, and the gear can be mounted, as covered by separate instructions. Then the mill can be taken to its location and set in place in the trunnion bearings.

If on the other hand the handling facilities are limited it is recommended that the bare shell and heads be assembled together in a slightly higher position than normal. After the flange bolts are tightened, the mill proper should be lowered into position. Other intermediate methods may be used, depending on local conditions.

In any event, just prior to the lowering of the mill into the bearings the trunnion journal and bushing and bases should be thoroughly cleaned and greased. Care should be taken not to foul the teeth in the gear or pinion. Trunnion bearing caps should be immediately installed, although not necessarily tightened, to prevent dirt settling on the trunnions. The gear should be at least tentatively covered for protection.

IMPORTANT. Unless the millwright or operator is familiar with this type of seal, there is a tendency to assume that the oil seal is too long because of its appearance when held firmly around the trunnion. It is not the function of the brass oil seal band to provide tension for effective sealing. This is accomplished by the garter spring which is provided with the oil seal.

Assemble the oil seal with the spring in place, and with the split at the top. Encircle the oil seal with the band, keeping the blocks on the side of the bearing at or near the horizontal center line so that when in place they will fit between the two dowel pins on the bearing, which are used to prevent rotation of the seal.

Moderately tighten up the cap screws at the blocks, pulling them together to thus hold the seal with its spring in place. If the blocks cannot be pulled snuggly together, then the oil seal may be cut accordingly. Oil the trunnion surface and slide the entire seal assembly back into place against the shoulder of the bearing and finish tightening. Install the retainer ring and splash ring as shown.

In most cases the trunnion liners are already mounted in the trunnions of the mills. If not, they should be assembled with attention being given to match marks or in some cases to dowel pins which are used to locate the trunnion liners in their proper relation to other parts.

If a scoop feeder, combination drum scoop feeder or drum feeder is supplied with the mill, it should be mounted on the extended flange of the feed trunnion liner, matching the dowel pin with its respective hole. The dowel pin arrangement is provided only where there is a spiral in the feed trunnion liner. This matching is important as it fixes the relationship between the discharge from the scoop and the internal spiral of the trunnion liner. Tighten the bolts attaching the feeder to the trunnion liner evenly, all around the circle, seating the feeder tightly and squarely on its bevelled seat. Check the bolts holding the lips and other bolts that may require tightening. The beveled seat design is used primarily where a feeder is provided for the trunnion to trunnion liner connection, and the trunnion liner to feeder connection. When a feeder is not used these connecting joints are usually provided by a simple cylindrical or male and female joint.

If a spout feeder is to be used, it is generally supplied by the user, and should be mounted independently of the mill. The spout should project inside the feed trunnion liner, but must not touch the liner or spiral.

Ordinarily the feed box for a scoop tender is designed and supplied by the user. The feed box should be so constructed that it has at least 6 clearance on both sides and at the bottom of the scoop. This clearance is measured from the outside of the feed scoop.

The feed box may be constructed of 2 wood, but more often is made of 3/16 or plate steel reinforced with angles. In the larger size mills, the lower portion is sometimes made of concrete. Necessary openings should be provided for the original feed and the sand returns from the classifiers when in closed circuit.

A plate steel gear guard is furnished with the mill for safety in operation and to protect the gear and pinion from dirt or grit. As soon as the gear and pinion have been cleaned and coated with the proper lubricant, the gear guard should be assembled and set on its foundation.

Most Rod Mills are provided with a discharge housing mechanism mounted independently of the mill. This unit consists of the housing proper, plug door, plug shaft, arm, and various hinge pins and pivot and lock pins. The door mechanism is extra heavy throughout and is subject to adjustment as regard location. Place the housing proper on the foundation, level with steel shims and tighten the foundation bolts. The various parts may now be assembled to the housing proper and the door plug can be swung into place, securing it with the necessary lock pins.

After the mill has been completely assembled and aligned, the door mechanism centered and adjusted, and all clearances checked, the housing base can be grouted. The unit should be so located both vertically and horizontally so as to provide a uniform annular opening between the discharge plug door and the head liners.

In some cases because of space limitation, economy reasons, etc., the mill is not equipped with separate discharge housing. In such a case, the open end low discharge principal is accomplished by means of the same size opening through the discharge trunnion but with the plug door attached to lugs on the head liner segments or lugs on the discharge trunnion liner proper. In still other cases, it is sometimes effected by means of an arm holding the plug and mounted on a cross member which is attached to the bell of the discharge trunnion liner. In such cases as those, a light weight sheet steel discharge housing is supplied by the user to accommodate the local plant layout in conjunction with the discharge launder.

TRUNNION BEARING LUBRICATION. For the larger mills with trunnion bearings provided with oil seals, we recommend flood oil lubrication. This can be accomplished by a centralized system for two or more mills, or by an individual system for each mill. We recommend the individual system for each mill, except where six or more mills are involved, or when economy reasons may dictate otherwise.

In any event oil flow to each trunnion bearing should be between 3 to 5 gallons per minute. The oil should be adequately filtered and heaters may be used to maintain a temperature which will provide proper filtration and maintain the necessary viscosity for adequate flow. The lines leading from the filter to the bearing should be of copper tubing or pickled piping. The drain line leading from the bearings to the storage or sump tank should be of adequate size for proper flow, and they should be set at a minimum slope of per foot, perferably per foot. Avoid unnecessary elbows and fittings wherever possible. Avoid bends which create traps and which might accumulate impurities. All lines should be thoroughly cleaned and flushed with a solvent, and then blown free with air, before oil is added.

It is advisable to interlock the oil pump motor with the mill motor in such a way that the mill cannot be started until after the oil pump is operating. We recommend the use of a non-adjuslable valve at each bearing to prevent tampering.

When using the drip oil system it is advisable to place wool yarn or waste inside a canvas porous bag to prevent small pieces of the wool being drawn down into the trunnion journal. If brick grease is used, care should be taken in its selection with regard to the range of its effective temperature. In other words, it should be pointed out that brick grease is generally designed for a specific temperature range. Where the bearing temperature does not come up to the minimum temperature rating of the brick grease, the oil will not flow from it, and on the other hand if the temperature of the bearing exceeds the maximum temperature rating of the brick grease, the brick is subject to glazing; therefore, blinding off of the oil. This brick should be trimmed so that it rests freely on the trunnion journal, and does not hang up, or bind on the sides of the grease box.

When replacing the brick grease, remove the old grease completely. Due to the extended running time of brick grease, there is usually an accumulation of impurities and foreign matter on the top surface, which is detrimental to the bearing.

Where anti-friction bearings are supplied, they are adequately sealed for either grease or oil lubrication. If a flood system is used for the trunnion bearings and it is adequately filtered, it can then be used for pinion bearings with the same precautions taken as mentioned above, with a flow of to 1 gallons per minute to each bearing.

These lubricants can be applied by hand, but we highly recommend some type of spray system, whether it be automatic, semi-automatic or manually operated. It has been found that it is best to lubricate gears frequently with small quantities.

Start the lubrication system and run it for about ten minutes, adjusting the oil flow at each bearing. Check all of the bolts and nuts on the mill for tightness and remove all ladders, tools and other obstructions prior to starting the mill.

Before starting the mill, even though it is empty, we recommend that it be jogged one or two revolutions for a check as to clearance of the gear and its guard, splash rings, etc. The trunnion journal should also be checked for uniform oil film and for any evidence of foreign material which might manifest itself through the appearance of scratches on the journal. If there are any scratches, it is very possible that some foreign material such as weld splatter may have been drawn down into the bushing, and can be found imbedded there. These particles should be removed before proceeding further.

If everything is found to be satisfactory, then the mill should be run for ten to fifteen minutes, and stopped. The trunnion bearings should be checked for any undue temperature and the gear grease pattern can be observed for uniformity which would indicate correct alignment.

It should be noted that with an empty mill the reactions and operating characteristics of the bearings and gearing at this point are somewhat different than when operating with a ball or rod charge. Gear noises will be prominent and some vibration will occur due to no load and normal back-lash. Furthermore, it will be found that the mill will continue to rotate for some time after the power is shut off. Safety precautions should therefore he observed, and no work should be done on the mill until it has come to a complete stop.

We have now reached the point where a half ball or rod charge can be added, and the mill run for another six to eight hours, feeding approximately half the anticipated tonnage. The mill should now be stopped, end the gear grease pattern checked, and gear and pinion mesh corrected, if necessary, according to separate instructions.

The full charge of balls or rods can now be added, as well as the full amount of feed, and after a run of about four to six days, ALL BOLTS SHOULD AGAIN BE RETIGHTENED, and the gear and pinion checked again, and adjusted if necessary.

Where starting jacks are provided for the trunnion bearings of the larger sized mills, they should be filled with the same oil that is used for the lubrication of the trunnion bearings. Before starting the mill they should be pumped so as to insure having an oil film between the journal and the bushing.

When relining any part of the mill, clean away all sand from the parts to be relined before putting in the new liners. For the head liners and shell liners you may then proceed in the same manner used at the time of the initial assembly.

Before relining the grate type discharge head, it is advisable to refer to the assembly drawings and the parts list.Because of such limitations as the size of the manhole opening, and for various other reasons, it will be found that the center discharge liner and cone designs vary. The cone may be a separate piece or integral with either the trunnion liner, or the router discharge liner. Furthermore, it will be found in some mills that the center discharge liner is held by bolts through the discharge head, whereas in other cases it depends upon the clamping effect of grates to hold it in position. In any event, the primary thing to remember in assembling the discharge grate head parts is the fact that the grate should be first drawn up tightly towards the center discharge liner by adjusting the grate set screws located at the periphery of the discharge head. This adjustment should be carried out in progressive steps, alternating at about 180 if possible and in such a manner that, the center discharge liner does not become dislodged from its proper position at the center of the mill. These grate set screws should be adjusted with the side clamp bar bolts loosened. After the grates have been completely tightened with the set screws, check for correct and uniform position of each grate section. The side clamp bar bolts may now be lightened, again using an alternate process. This should result in the side clamp bars firmly bearing against the beveled sides of the grates. The side clamp bars should not hear against the lifter liners.

When new pan liners are installed, they should be grouted in position so as to prevent pulp race in the void space between the discharge head and the pan liner. Another good method of preventing this pulp race is the use of the sponge rubber which can be cemented in place.

After the mill is erected, in order to avoid overlooking both obvious and obscure installation details, we recommend the use of a check list. This is particularly recommended for multiple mill installations where it is difficult to control the different phases of installation for each and every mill. Such a check list can be modeled after the following:

No. 1 Connecting Bolts drawn tight. A. Head and Shell flange bolts. B. Gear Connecting, bolts. No. 2 Trunnion studs or bolts drawn up tight. No. 3 Trunnion liner and feeder connecting bolts or studs drawn up tight. No. 4 Feeder lip bolts tightened. No. 5 Liner bolts drawn up tight. No. 6 Gear. A. Concentric B. Backlash C. Runout D. Joint bolts drawn up tight. No. 7 Coupling and Drive alignment and lubrication. No. 8 Bearings and Gearing cleaned and lubricated. No. 9 Lubrication system in working order with automatic devices including alarms and interlocking systems.

We further recommend that during the first thirty to sixty days of operation, particular attention be given to bolt tightness, foundation settlement and condition of the grouting. We suggest any unusual occurrence be recorded so that should trouble develop later there may be a clue which would simplify diagnosing and rectifying the situation.

As a safety precaution, and in many cases in order to comply with local safety regulations, guards should be used to protect the operators and mechanics from contact with moving parts. However, these guards should not be of such a design that will prevent or hinder the close inspection of the vital parts. Frequent inspection should be made at regular intervals with particular attention being given to the condition of the wearing parts in the mill. In this way, you will be better able to anticipate your needs for liners and other parts in time to comply with the current delivery schedules.

When ordering repair or replacement parts for your mill, be sure to identify the parts with the number and description as shown on the repair parts list, and specify the hand and serial number of the mill.

By following the instructions outlined in this manual, mechanical malfunctions will be eliminated. However, inadvertent errors may occur even under, the most careful supervision. With this in mind, it is possible that some difficulties may arise. Whenever any abnormal mechanical reactions are found, invariably they can be attributed to causes which though sometimes obvious are often hidden. We sight herewith the most common problems, with their solutions.

Cause A GROUT DISINTEGRATION. Very often when the grouting is not up to specification the vibration from the mill tends to disintegrate the grouting. In most instances the disintegration starts between the sole plate and the top surface of the grouting near or at the vertical centerline of the mill. As this continues, the weight of the mill causes the sole plate and trunnion bearing base to bend with a resultant pinching action at the side of the bearing near the horizontal center line of the mill. This pinching will cut off and wipe the oil film from the journal and will manifest itself in the same manner as if the lubrication supply had been cut off. If the grout disintegration is limited to about . 050 and does not appear to be progressing further, the situation can be corrected by applying a corresponding amount of shimming between the trunnion bearing base and the sole plate near the centerline of the mill in such a fashion that the trunnion bearing base has been returned to its normal dimensional position. If, on the other hand, the grouting is in excess of . 050 and appears to be progressing further, it is advisable to shut down operations until the sole plate has been re grouted.

Cause B HIGH SPOT ON THE BUSHING. While all BallMill bushings are scraped in the shop to fit either a jig mandrel or the head proper to which it is to be fitted, nevertheless there is a certain amount of seasoning and dimensional change which goes on in the type of metals used. Therefore if high spots are found, the mill should be raised, the bushings removed and rescraped. Bluing may be used to assist in detecting high spots.

Cause C INSUFFICIENT OIL FLOW. Increase the oil supply if it is a flood oil system. If brick grease is used, it is possible that the particular grade of brick may not be applicable to the actual bearing temperature. Refer to the remarks in this manual under the paragraph entitled Lubrication.

Cause E EXCESSIVE RUBBING ON THE SIDE OF THE BUSHING. This comes about due to the improper setting of the bearings in the longitudinal plane. In some cases, particularly on dry grinding or hot clinker grinding mills, the expansion of the mills proper may account for this condition. In any event, it can be remedied by re-adjusting the bearing base on the sole plate longitudinally at the end opposite the drive.

There are many more lubricant suppliers, such as E. F. Houghton and Co. , or Lubriplate Division of Fiske Bros. Refining Co. In making your final selection of lubricants, you should consider the actual plant conditions as well as the standardization of lubricants. New and improved lubricants are being marketed, and we, therefore, suggest that you consult your local suppliers.

ball milling - an overview | sciencedirect topics

Ball milling technique, using mechanical alloying and mechanical milling approaches were proposed to the word wide in the 8th decade of the last century for preparing a wide spectrum of powder materials and their alloys. In fact, ball milling process is not new and dates back to more than 150 years. It has been used in size comminutions of ore, mineral dressing, preparing talc powders and many other applications. It might be interesting for us to have a look at the history and development of ball milling and the corresponding products. The photo shows the STEM-BF image of a Cu-based alloy nanoparticle prepared by mechanical alloying (After El-Eskandarany, unpublished work, 2014).

Ball milling is often used not only for grinding powders but also for oxides or nanocomposite synthesis and/or structure/phase composition optimization [14,41]. Mechanical activation by ball milling is known to increase the material reactivity and uniformity of spatial distribution of elements [63]. Thus, postsynthesis processing of the materials by ball milling can help with the problem of minor admixture forming during cooling under air after high-temperature sintering due to phase instability.

Ball milling, a shear-force dominant process where the particle size goes on reducing by impact and attrition mainly consists of metallic balls (generally Zirconia (ZrO2) or steel balls), acting as grinding media and rotating shell to create centrifugal force. In this process, graphite (precursor) was breakdown by randomly striking with grinding media in the rotating shell to create shear and compression force which helps to overcome the weak Vander Waal's interaction between the graphite layers and results in their splintering. Fig. 4A schematic illustrates ball milling process for graphene preparation. Initially, because of large size of graphite, compressive force dominates and as the graphite gets fragmented, shear force cleaves graphite to produce graphene. However, excessive compression force may damage the crystalline properties of graphene and hence needs to be minimized by controlling the milling parameters e.g. milling duration, milling revolution per minute (rpm), ball-to-graphite/powder ratio (B/P), initial graphite weight, ball diameter. High quality graphene can be achieved under low milling speed; though it will increase the processing time which is highly undesirable for large scale production.

Fig. 4. (A) Schematic illustration of graphene preparation via ball milling. SEM images of bulk graphite (B), GSs/E-H (C) GSs/K (D); (E) and (F) are the respective TEM images; (G) Raman spectra of bulk graphite versus GSs exfoliated via wet milling in E-H and K.

Milling of graphite layers can be instigated in two states: (i) dry ball milling (DBM) and (ii) wet ball milling (WBM). WBM process requires surfactant/solvent such as N,N Dimethylformamide (DMF) [22], N-methylpyrrolidone (NMP) [26], deionized (DI) water [27], potassium acetate [28], 2-ethylhexanol (E-H) [29] and kerosene (K) [29] etc. and is comparatively simpler as compared with DBM. Fig. 4BD show the scanning electron microscopy (SEM) images of bulk graphite, graphene sheets (GSs) prepared in E-H (GSs/E-H) and K (GSs/K), respectively; the corresponding transmission electron microscopy (TEM) images and the Raman spectra are shown in Fig. 4EG, respectively [29].

Compared to this, DBM requires several milling agents e.g. sodium chloride (NaCl) [30], Melamine (Na2SO4) [31,32] etc., along with the metal balls to reduce the stress induced in graphite microstructures, and hence require additional purification for exfoliant's removal. Na2SO4 can be easily washed away by hot water [19] while ammonia-borane (NH3BH3), another exfoliant used to weaken the Vander Waal's bonding between graphite layers can be using ethanol [33]. Table 1 list few ball milling processes carried out using various milling agent (in case of DBM) and solvents (WBM) under different milling conditions.

Ball milling as a mechanochemical technique has been extensively used for grinding of materials to fine particles and for the formation and modification of inorganic solids. Mechanochemistry is a branch of solid-state chemistry in which intramolecular bonds are broken mechanically by using an external mechanical energy followed by additional chemical reactions [109]. Its use in synthetic organic chemistry is comparatively limited but has attained more attention during the last decade. A study proposed the importance of ball milling in synthetic organic chemistry, which has been widely documented [110]. Many reports in the literature have shown that high-speed ball milling (HSBM) is appropriate for a variety of organic transformations and for the expansion of environmentally benevolent chemical reactions [111, 112]. HSBM in solvent-free circumstances is considered as a feasible alternative to wet chemistry. It is based on the similar principles as that of mortar and pestle, which utilizes mechanical actions to convert reactants to products during the course of the reaction [113, 114]. The mills are effective at creating small particle sizes, which has allowed them to demonstrate their amazing characteristics. The ball milling time is an important factor in nanostructure materials synthesis. It has been demonstrated that an increase in the milling time increases microhardness of synthesized materials [115]. Different numbers, sizes, shapes, and materials of the ball bearings used could influence mixing and impact energy and thus the efficiency of the reaction. Using no ball bearing predictably gave the least amount of mixing and energy resulting in the lowest percent conversion to product.

Reactive ball-milling (RBM) technique has been considered as a powerful tool for fabrication of metallic nitrides and hydrides via room temperature ball milling. The flowchart shows the mechanism of gas-solid reaction through RBM that was proposed by El-Eskandarany. In his model, the starting metallic powders are subjected to dramatic shear and impact forces that are generated by the ball-milling media. The powders are, therefore, disintegrated into smaller particles, and very clean or fresh oxygen-free active surfaces of the powders are created. The reactive milling atmosphere (nitrogen or hydrogen gases) was gettered and absorbed completely by the first atomically clean surfaces of the metallic ball-milled powders to react in a same manner as a gas-solid reaction owing to the mechanically induced reactive milling.

Ball milling is a grinding method that grinds nanotubes into extremely fine powders. During the ball milling process, the collision between the tiny rigid balls in a concealed container will generate localized high pressure. Usually, ceramic, flint pebbles and stainless steel are used.25 In order to further improve the quality of dispersion and introduce functional groups onto the nanotube surface, selected chemicals can be included in the container during the process. The factors that affect the quality of dispersion include the milling time, rotational speed, size of balls and balls/ nanotube amount ratio. Under certain processing conditions, the particles can be ground to as small as 100nm. This process has been employed to transform carbon nanotubes into smaller nanoparticles, to generate highly curved or closed shell carbon nanostructures from graphite, to enhance the saturation of lithium composition in SWCNTs, to modify the morphologies of cup-stacked carbon nanotubes and to generate different carbon nanoparticles from graphitic carbon for hydrogen storage application.25 Even though ball milling is easy to operate and suitable for powder polymers or monomers, process-induced damage on the nanotubes can occur.

Ball milling is a way to exfoliate graphite using lateral force, as opposed to the Scotch Tape or sonication that mainly use normal force. Ball mills, like the three roll machine, are a common occurrence in industry, for the production of fine particles. During the ball milling process, there are two factors that contribute to the exfoliation. The main factor contributing is the shear force applied by the balls. Using only shear force, one can produce large graphene flakes. The secondary factor is the collisions that occur during milling. Harsh collisions can break these large flakes and can potentially disrupt the crystal structure resulting in a more amorphous mass. So in order to create good-quality, high-area graphene, the collisions have to be minimized.

The ball-milling process is common in grinding machines as well as in reactors where various functional materials can be created by mechanochemical synthesis. A simple milling process reduces both CO2 generation and energy consumption during materials production. Herein a novel mechanochemical approach 1-3) to produce sophisticated carbon nanomaterials is reported. It is demonstrated that unique carbon nanostructures including carbon nanotubes and carbon onions are synthesized by high-speed ball-milling of steel balls. It is considered that the gas-phase reaction takes place around the surface of steel balls under local high temperatures induced by the collision-friction energy in ball-milling process, which results in phase separated unique carbon nanomaterials.

Ball milling is another technique which was reported very recently for the production of NFC. In this method, a cellulose suspension is placed in a hollow cylindrical container, partially filled with balls (e.g., ceramic, zirconia, or metal). While the container rotates, cellulose is disintegrated by the high energy collision between the balls. Zhang etal. [114] studied the process of NFC production from once-dried bleached softwood kraft pulp suspension at a solid concentration of 1wt% using ball milling. They showed the influence of the process conditions such as the ball size and ball-to-cellulose weight ratio on the morphology of the produced NFC. An average diameter of 100nm was reported for the disintegrated fibers. The control of the processing parameters was necessary to prevent cellulose decrystallization and to produce cellulose nanofibers rather than short particles.

Ball milling is one of the earliest approach for BNNTs synthesis [59]. The process involves extensive ball milling of boron powder for a long period of time (up to 150h) in NH3 gas followed by annealing at high temperature (up to 1300C) in N2 environment. It was suggested that a nitriding reaction was induced between boron powder and NH3 gas due to high energy milling, resulting in metastable disordered BN nanostructures and boron nanoparticles. BNNTs were grown from these reactive phase during a subsequent high-temperature annealing of the powder in ammonia ambient. It is proposed that BN nanoparticles formed during the milling process act as nucleation sites for growth during annealing process. Apart from them, contaminant Fe nanoparticles introduced during the milling process also served as catalyst for the growth. However, the quality and purity of BNNTs grown by ball milling was not satisfactory.

In the following years, various works have been done to increase the throughput and improve quality of BNNTs using ball-milling process. Li et. al. showed that addition of catalyst during the milling process can help to increase the production yield [60]. As an example, boron powder and 10% of Fe(NO3)3 was milled in NH3 atmosphere at 250 KPa pressure. Annealing the milled powder at N2+15% H2 gas environment at 1100C mostly resulted in bamboo-like BNNTs. Heating the same milled powder at 1300C in NH3 environment resulted in the growth of cylindrical BNNTs with diameters approximately 10nm. Other metal-based compounds such as nickel boride (NiBx) [61] and Li2O [62] are also reported as catalysts to enhance the yield of BNNTs growth. Though large quantity of BNNTs can be synthesized via this process, shortcoming was that the BNNTs are usually bamboo-like structured and contain B/BN reactants (amorphous boron particles and BN bulky flakes) as impurities.

ball mills - an overview | sciencedirect topics

A ball mill is a type of grinder used to grind and blend bulk material into QDs/nanosize using different sized balls. The working principle is simple; impact and attrition size reduction take place as the ball drops from near the top of a rotating hollow cylindrical shell. The nanostructure size can be varied by varying the number and size of balls, the material used for the balls, the material used for the surface of the cylinder, the rotation speed, and the choice of material to be milled. Ball mills are commonly used for crushing and grinding the materials into an extremely fine form. The ball mill contains a hollow cylindrical shell that rotates about its axis. This cylinder is filled with balls that are made of stainless steel or rubber to the material contained in it. Ball mills are classified as attritor, horizontal, planetary, high energy, or shaker.

Grinding elements in ball mills travel at different velocities. Therefore, collision force, direction and kinetic energy between two or more elements vary greatly within the ball charge. Frictional wear or rubbing forces act on the particles, as well as collision energy. These forces are derived from the rotational motion of the balls and movement of particles within the mill and contact zones of colliding balls.

By rotation of the mill body, due to friction between mill wall and balls, the latter rise in the direction of rotation till a helix angle does not exceed the angle of repose, whereupon, the balls roll down. Increasing of rotation rate leads to growth of the centrifugal force and the helix angle increases, correspondingly, till the component of weight strength of balls become larger than the centrifugal force. From this moment the balls are beginning to fall down, describing during falling certain parabolic curves (Figure 2.7). With the further increase of rotation rate, the centrifugal force may become so large that balls will turn together with the mill body without falling down. The critical speed n (rpm) when the balls are attached to the wall due to centrifugation:

where Dm is the mill diameter in meters. The optimum rotational speed is usually set at 6580% of the critical speed. These data are approximate and may not be valid for metal particles that tend to agglomerate by welding.

The degree of filling the mill with balls also influences productivity of the mill and milling efficiency. With excessive filling, the rising balls collide with falling ones. Generally, filling the mill by balls must not exceed 3035% of its volume.

The mill productivity also depends on many other factors: physical-chemical properties of feed material, filling of the mill by balls and their sizes, armor surface shape, speed of rotation, milling fineness and timely moving off of ground product.

where b.ap is the apparent density of the balls; l is the degree of filling of the mill by balls; n is revolutions per minute; 1, and 2 are coefficients of efficiency of electric engine and drive, respectively.

A feature of ball mills is their high specific energy consumption; a mill filled with balls, working idle, consumes approximately as much energy as at full-scale capacity, i.e. during grinding of material. Therefore, it is most disadvantageous to use a ball mill at less than full capacity.

Grinding elements in ball mills travel at different velocities. Therefore, collision force, direction, and kinetic energy between two or more elements vary greatly within the ball charge. Frictional wear or rubbing forces act on the particles as well as collision energy. These forces are derived from the rotational motion of the balls and the movement of particles within the mill and contact zones of colliding balls.

By the rotation of the mill body, due to friction between the mill wall and balls, the latter rise in the direction of rotation until a helix angle does not exceed the angle of repose, whereupon the balls roll down. Increasing the rotation rate leads to the growth of the centrifugal force and the helix angle increases, correspondingly, until the component of the weight strength of balls becomes larger than the centrifugal force. From this moment, the balls are beginning to fall down, describing certain parabolic curves during the fall (Fig. 2.10).

With the further increase of rotation rate, the centrifugal force may become so large that balls will turn together with the mill body without falling down. The critical speed n (rpm) when the balls remain attached to the wall with the aid of centrifugal force is:

where Dm is the mill diameter in meters. The optimum rotational speed is usually set at 65%80% of the critical speed. These data are approximate and may not be valid for metal particles that tend to agglomerate by welding.

where db.max is the maximum size of the feed (mm), is the compression strength (MPa), E is the modulus of elasticity (MPa), b is the density of material of balls (kg/m3), and D is the inner diameter of the mill body (m).

The degree of filling the mill with balls also influences the productivity of the mill and milling efficiency. With excessive filling, the rising balls collide with falling ones. Generally, filling the mill by balls must not exceed 30%35% of its volume.

The productivity of ball mills depends on the drum diameter and the relation of drum diameter and length. The optimum ratio between length L and diameter D, L:D, is usually accepted in the range 1.561.64. The mill productivity also depends on many other factors, including the physical-chemical properties of the feed material, the filling of the mill by balls and their sizes, the armor surface shape, the speed of rotation, the milling fineness, and the timely moving off of the ground product.

where D is the drum diameter, L is the drum length, b.ap is the apparent density of the balls, is the degree of filling of the mill by balls, n is the revolutions per minute, and 1, and 2 are coefficients of efficiency of electric engine and drive, respectively.

A feature of ball mills is their high specific energy consumption. A mill filled with balls, working idle, consumes approximately as much energy as at full-scale capacity, that is, during the grinding of material. Therefore, it is most disadvantageous to use a ball mill at less than full capacity.

Milling time in tumbler mills is longer to accomplish the same level of blending achieved in the attrition or vibratory mill, but the overall productivity is substantially greater. Tumbler mills usually are used to pulverize or flake metals, using a grinding aid or lubricant to prevent cold welding agglomeration and to minimize oxidation [23].

Cylindrical Ball Mills differ usually in steel drum design (Fig. 2.11), which is lined inside by armor slabs that have dissimilar sizes and form a rough inside surface. Due to such juts, the impact force of falling balls is strengthened. The initial material is fed into the mill by a screw feeder located in a hollow trunnion; the ground product is discharged through the opposite hollow trunnion.

Cylindrical screen ball mills have a drum with spiral curved plates with longitudinal slits between them. The ground product passes into these slits and then through a cylindrical sieve and is discharged via the unloading funnel of the mill body.

Conical Ball Mills differ in mill body construction, which is composed of two cones and a short cylindrical part located between them (Fig. 2.12). Such a ball mill body is expedient because efficiency is appreciably increased. Peripheral velocity along the conical drum scales down in the direction from the cylindrical part to the discharge outlet; the helix angle of balls is decreased and, consequently, so is their kinetic energy. The size of the disintegrated particles also decreases as the discharge outlet is approached and the energy used decreases. In a conical mill, most big balls take up a position in the deeper, cylindrical part of the body; thus, the size of the balls scales down in the direction of the discharge outlet.

For emptying, the conical mill is installed with a slope from bearing to one. In wet grinding, emptying is realized by the decantation principle, that is, by means of unloading through one of two trunnions.

With dry grinding, these mills often work in a closed cycle. A scheme of the conical ball mill supplied with an air separator is shown in Fig. 2.13. Air is fed to the mill by means of a fan. Carried off by air currents, the product arrives at the air separator, from which the coarse particles are returned by gravity via a tube into the mill. The finished product is trapped in a cyclone while the air is returned in the fan.

The ball mill is a tumbling mill that uses steel balls as the grinding media. The length of the cylindrical shell is usually 11.5 times the shell diameter (Figure 8.11). The feed can be dry, with less than 3% moisture to minimize ball coating, or slurry containing 2040% water by weight. Ball mills are employed in either primary or secondary grinding applications. In primary applications, they receive their feed from crushers, and in secondary applications, they receive their feed from rod mills, AG mills, or SAG mills.

Ball mills are filled up to 40% with steel balls (with 3080mm diameter), which effectively grind the ore. The material that is to be ground fills the voids between the balls. The tumbling balls capture the particles in ball/ball or ball/liner events and load them to the point of fracture.

When hard pebbles rather than steel balls are used for the grinding media, the mills are known as pebble mills. As mentioned earlier, pebble mills are widely used in the North American taconite iron ore operations. Since the weight of pebbles per unit volume is 3555% of that of steel balls, and as the power input is directly proportional to the volume weight of the grinding medium, the power input and capacity of pebble mills are correspondingly lower. Thus, in a given grinding circuit, for a certain feed rate, a pebble mill would be much larger than a ball mill, with correspondingly a higher capital cost. However, the increase in capital cost is justified economically by a reduction in operating cost attributed to the elimination of steel grinding media.

In general, ball mills can be operated either wet or dry and are capable of producing products in the order of 100m. This represents reduction ratios of as great as 100. Very large tonnages can be ground with these ball mills because they are very effective material handling devices. Ball mills are rated by power rather than capacity. Today, the largest ball mill in operation is 8.53m diameter and 13.41m long with a corresponding motor power of 22MW (Toromocho, private communications).

Modern ball mills consist of two chambers separated by a diaphragm. In the first chamber the steel-alloy balls (also described as charge balls or media) are about 90mm diameter. The mill liners are designed to lift the media as the mill rotates, so the comminution process in the first chamber is dominated by crushing. In the second chamber the ball diameters are of smaller diameter, between 60 and 15mm. In this chamber the lining is typically a classifying lining which sorts the media so that ball size reduces towards the discharge end of the mill. Here, comminution takes place in the rolling point-contact zone between each charge ball. An example of a two chamber ball mill is illustrated in Fig. 2.22.15

Much of the energy consumed by a ball mill generates heat. Water is injected into the second chamber of the mill to provide evaporative cooling. Air flow through the mill is one medium for cement transport but also removes water vapour and makes some contribution to cooling.

Grinding is an energy intensive process and grinding more finely than necessary wastes energy. Cement consists of clinker, gypsum and other components mostly more easily ground than clinker. To minimise over-grinding modern ball mills are fitted with dynamic separators (otherwise described as classifiers or more simply as separators). The working principle is that cement is removed from the mill before over-grinding has taken place. The cement is then separated into a fine fraction, which meets finished product requirements, and a coarse fraction which is returned to mill inlet. Recirculation factor, that is, the ratio of mill throughput to fresh feed is up to three. Beyond this, efficiency gains are minimal.

For more than 50years vertical mills have been the mill of choice for grinding raw materials into raw meal. More recently they have become widely used for cement production. They have lower specific energy consumption than ball mills and the separator, as in raw mills, is integral with the mill body.

In the Loesche mill, Fig. 2.23,16 two pairs of rollers are used. In each pair the first, smaller diameter, roller stabilises the bed prior to grinding which takes place under the larger roller. Manufacturers use different technologies for bed stabilisation.

Comminution in ball mills and vertical mills differs fundamentally. In a ball mill, size reduction takes place by impact and attrition. In a vertical mill the bed of material is subject to such a high pressure that individual particles within the bed are fractured, even though the particles are very much smaller than the bed thickness.

Early issues with vertical mills, such as narrower PSD and modified cement hydration characteristics compared with ball mills, have been resolved. One modification has been to install a hot gas generator so the gas temperature is high enough to partially dehydrate the gypsum.

For many decades the two-compartment ball mill in closed circuit with a high-efficiency separator has been the mill of choice. In the last decade vertical mills have taken an increasing share of the cement milling market, not least because the specific power consumption of vertical mills is about 30% less than that of ball mills and for finely ground cement less still. The vertical mill has a proven track record in grinding blastfurnace slag, where it has the additional advantage of being a much more effective drier of wet feedstock than a ball mill.

The vertical mill is more complex but its installation is more compact. The relative installed capital costs tend to be site specific. Historically the installed cost has tended to be slightly higher for the vertical mill.

Special graph paper is used with lglg(1/R(x)) on the abscissa and lg(x) on the ordinate axes. The higher the value of n, the narrower the particle size distribution. The position parameter is the particle size with the highest mass density distribution, the peak of the mass density distribution curve.

Vertical mills tend to produce cement with a higher value of n. Values of n normally lie between 0.8 and 1.2, dependent particularly on cement fineness. The position parameter is, of course, lower for more finely ground cements.

Separator efficiency is defined as specific power consumption reduction of the mill open-to-closed-circuit with the actual separator, compared with specific power consumption reduction of the mill open-to-closed-circuit with an ideal separator.

As shown in Fig. 2.24, circulating factor is defined as mill mass flow, that is, fresh feed plus separator returns. The maximum power reduction arising from use of an ideal separator increases non-linearly with circulation factor and is dependent on Rf, normally based on residues in the interval 3245m. The value of the comminution index, W, is also a function of Rf. The finer the cement, the lower Rf and the greater the maximum power reduction. At C = 2 most of maximum power reduction is achieved, but beyond C = 3 there is very little further reduction.

Separator particle separation performance is assessed using the Tromp curve, a graph of percentage separator feed to rejects against particle size range. An example is shown in Fig. 2.25. Data required is the PSD of separator feed material and of rejects and finished product streams. The bypass and slope provide a measure of separator performance.

The particle size is plotted on a logarithmic scale on the ordinate axis. The percentage is plotted on the abscissa either on a linear (as shown here) or on a Gaussian scale. The advantage of using the Gaussian scale is that the two parts of the graph can be approximated by two straight lines.

The measurement of PSD of a sample of cement is carried out using laser-based methodologies. It requires a skilled operator to achieve consistent results. Agglomeration will vary dependent on whether grinding aid is used. Different laser analysis methods may not give the same results, so for comparative purposes the same method must be used.

The ball mill is a cylindrical drum (or cylindrical conical) turning around its horizontal axis. It is partially filled with grinding bodies: cast iron or steel balls, or even flint (silica) or porcelain bearings. Spaces between balls or bearings are occupied by the load to be milled.

Following drum rotation, balls or bearings rise by rolling along the cylindrical wall and descending again in a cascade or cataract from a certain height. The output is then milled between two grinding bodies.

Ball mills could operate dry or even process a water suspension (almost always for ores). Dry, it is fed through a chute or a screw through the units opening. In a wet path, a system of scoops that turn with the mill is used and it plunges into a stationary tank.

Mechanochemical synthesis involves high-energy milling techniques and is generally carried out under controlled atmospheres. Nanocomposite powders of oxide, nonoxide, and mixed oxide/nonoxide materials can be prepared using this method. The major drawbacks of this synthesis method are: (1) discrete nanoparticles in the finest size range cannot be prepared; and (2) contamination of the product by the milling media.

More or less any ceramic composite powder can be synthesized by mechanical mixing of the constituent phases. The main factors that determine the properties of the resultant nanocomposite products are the type of raw materials, purity, the particle size, size distribution, and degree of agglomeration. Maintaining purity of the powders is essential for avoiding the formation of a secondary phase during sintering. Wet ball or attrition milling techniques can be used for the synthesis of homogeneous powder mixture. Al2O3/SiC composites are widely prepared by this conventional powder mixing route by using ball milling [70]. However, the disadvantage in the milling step is that it may induce certain pollution derived from the milling media.

In this mechanical method of production of nanomaterials, which works on the principle of impact, the size reduction is achieved through the impact caused when the balls drop from the top of the chamber containing the source material.

A ball mill consists of a hollow cylindrical chamber (Fig. 6.2) which rotates about a horizontal axis, and the chamber is partially filled with small balls made of steel, tungsten carbide, zirconia, agate, alumina, or silicon nitride having diameter generally 10mm. The inner surface area of the chamber is lined with an abrasion-resistant material like manganese, steel, or rubber. The magnet, placed outside the chamber, provides the pulling force to the grinding material, and by changing the magnetic force, the milling energy can be varied as desired. The ball milling process is carried out for approximately 100150h to obtain uniform-sized fine powder. In high-energy ball milling, vacuum or a specific gaseous atmosphere is maintained inside the chamber. High-energy mills are classified into attrition ball mills, planetary ball mills, vibrating ball mills, and low-energy tumbling mills. In high-energy ball milling, formation of ceramic nano-reinforcement by in situ reaction is possible.

It is an inexpensive and easy process which enables industrial scale productivity. As grinding is done in a closed chamber, dust, or contamination from the surroundings is avoided. This technique can be used to prepare dry as well as wet nanopowders. Composition of the grinding material can be varied as desired. Even though this method has several advantages, there are some disadvantages. The major disadvantage is that the shape of the produced nanoparticles is not regular. Moreover, energy consumption is relatively high, which reduces the production efficiency. This technique is suitable for the fabrication of several nanocomposites, which include Co- and Cu-based nanomaterials, Ni-NiO nanocomposites, and nanocomposites of Ti,C [71].

Planetary ball mill was used to synthesize iron nanoparticles. The synthesized nanoparticles were subjected to the characterization studies by X-ray diffraction (XRD), and scanning electron microscopy (SEM) techniques using a SIEMENS-D5000 diffractometer and Hitachi S-4800. For the synthesis of iron nanoparticles, commercial iron powder having particles size of 10m was used. The iron powder was subjected to planetary ball milling for various period of time. The optimum time period for the synthesis of nanoparticles was observed to be 10h because after that time period, chances of contamination inclined and the particles size became almost constant so the powder was ball milled for 10h to synthesize nanoparticles [11]. Fig. 12 shows the SEM image of the iron nanoparticles.

The vibratory ball mill is another kind of high-energy ball mill that is used mainly for preparing amorphous alloys. The vials capacities in the vibratory mills are smaller (about 10 ml in volume) compared to the previous types of mills. In this mill, the charge of the powder and milling tools are agitated in three perpendicular directions (Fig. 1.6) at very high speed, as high as 1200 rpm.

Another type of the vibratory ball mill, which is used at the van der Waals-Zeeman Laboratory, consists of a stainless steel vial with a hardened steel bottom, and a single hardened steel ball of 6 cm in diameter (Fig. 1.7).

The mill is evacuated during milling to a pressure of 106 Torr, in order to avoid reactions with a gas atmosphere.[44] Subsequently, this mill is suitable for mechanical alloying of some special systems that are highly reactive with the surrounding atmosphere, such as rare earth elements.

In spite of the traditional approaches used for gas-solid reaction at relatively high temperature, Calka etal.[58] and El-Eskandarany etal.[59] proposed a solid-state approach, the so-called reactive ball milling (RBM), used for preparations different families of meal nitrides and hydrides at ambient temperature. This mechanically induced gas-solid reaction can be successfully achieved, using either high- or low-energy ball-milling methods, as shown in Fig.9.5. However, high-energy ball mill is an efficient process for synthesizing nanocrystalline MgH2 powders using RBM technique, it may be difficult to scale up for matching the mass production required by industrial sector. Therefore, from a practical point of view, high-capacity low-energy milling, which can be easily scaled-up to produce large amount of MgH2 fine powders, may be more suitable for industrial mass production.

In both approaches but with different scale of time and milling efficiency, the starting Mg metal powders milled under hydrogen gas atmosphere are practicing to dramatic lattice imperfections such as twinning and dislocations. These defects are caused by plastics deformation coupled with shear and impact forces generated by the ball-milling media.[60] The powders are, therefore, disintegrated into smaller particles with large surface area, where very clean or fresh oxygen-free active surfaces of the powders are created. Moreover, these defects, which are intensively located at the grain boundaries, lead to separate micro-scaled Mg grains into finer grains capable to getter hydrogen by the first atomically clean surfaces to form MgH2 nanopowders.

Fig.9.5 illustrates common lab scale procedure for preparing MgH2 powders, starting from pure Mg powders, using RBM via (1) high-energy and (2) low-energy ball milling. The starting material can be Mg-rods, in which they are processed via sever plastic deformation,[61] using for example cold-rolling approach,[62] as illustrated in Fig.9.5. The heavily deformed Mg-rods obtained after certain cold rolling passes can be snipped into small chips and then ball-milled under hydrogen gas to produce MgH2 powders.[8]

Planetary ball mills are the most popular mills used in scientific research for synthesizing MgH2 nanopowders. In this type of mill, the ball-milling media have considerably high energy, because milling stock and balls come off the inner wall of the vial and the effective centrifugal force reaches up to 20 times gravitational acceleration. The centrifugal forces caused by the rotation of the supporting disc and autonomous turning of the vial act on the milling charge (balls and powders). Since the turning directions of the supporting disc and the vial are opposite, the centrifugal forces alternately are synchronized and opposite. Therefore, the milling media and the charged powders alternatively roll on the inner wall of the vial, and are lifted and thrown off across the bowl at high speed.

In the typical experimental procedure, a certain amount of the Mg (usually in the range between 3 and 10g based on the vials volume) is balanced inside an inert gas atmosphere (argon or helium) in a glove box and sealed together with certain number of balls (e.g., 2050 hardened steel balls) into a hardened steel vial (Fig.9.5A and B), using, for example, a gas-temperature-monitoring system (GST). With the GST system, it becomes possible to monitor the progress of the gas-solid reaction taking place during the RBM process, as shown in Fig.9.5C and D. The temperature and pressure changes in the system during milling can be also used to realize the completion of the reaction and the expected end product during the different stages of milling (Fig.9.5D). The ball-to-powder weight ratio is usually selected to be in the range between 10:1 and 50:1. The vial is then evacuated to the level of 103bar before introducing H2 gas to fill the vial with a pressure of 550bar (Fig.9.5B). The milling process is started by mounting the vial on a high-energy ball mill operated at ambient temperature (Fig.9.5C).

Tumbling mill is cylindrical shell (Fig.9.6AC) that rotates about a horizontal axis (Fig.9.6D). Hydrogen gas is pressurized into the vial (Fig.9.6C) together with Mg powders and ball-milling media, using ball-to-powder weight ratio in the range between 30:1 and 100:1. Mg powder particles meet the abrasive and impacting force (Fig.9.6E), which reduce the particle size and create fresh-powder surfaces (Fig.9.6F) ready to react with hydrogen milling atmosphere.

Figure 9.6. Photographs taken from KISR-EBRC/NAM Lab, Kuwait, show (A) the vial and milling media (balls) and (B) the setup performed to charge the vial with 50bar of hydrogen gas. The photograph in (C) presents the complete setup of GST (supplied by Evico-magnetic, Germany) system prior to start the RBM experiment for preparing of MgH2 powders, using Planetary Ball Mill P400 (provided by Retsch, Germany). GST system allows us to monitor the progress of RBM process, as indexed by temperature and pressure versus milling time (D).

The useful kinetic energy in tumbling mill can be applied to the Mg powder particles (Fig.9.7E) by the following means: (1) collision between the balls and the powders; (2) pressure loading of powders pinned between milling media or between the milling media and the liner; (3) impact of the falling milling media; (4) shear and abrasion caused by dragging of particles between moving milling media; and (5) shock-wave transmitted through crop load by falling milling media. One advantage of this type of mill is that large amount of the powders (100500g or more based on the mill capacity) can be fabricated for each milling run. Thus, it is suitable for pilot and/or industrial scale of MgH2 production. In addition, low-energy ball mill produces homogeneous and uniform powders when compared with the high-energy ball mill. Furthermore, such tumbling mills are cheaper than high-energy mills and operated simply with low-maintenance requirements. However, this kind of low-energy mill requires long-term milling time (more than 300h) to complete the gas-solid reaction and to obtain nanocrystalline MgH2 powders.

Figure 9.7. Photos taken from KISR-EBRC/NAM Lab, Kuwait, display setup of a lab-scale roller mill (1000m in volume) showing (A) the milling tools including the balls (milling media and vial), (B) charging Mg powders in the vial inside inert gas atmosphere glove box, (C) evacuation setup and pressurizing hydrogen gas in the vial, and (D) ball milling processed, using a roller mill. Schematic presentations show the ball positions and movement inside the vial of a tumbler mall mill at a dynamic mode is shown in (E), where a typical ball-powder-ball collusion for a low energy tumbling ball mill is presented in (F).