malachite recovery in copper extraction flotation

copper flotation

Although basic porphyry copper flotation and metallurgy has remained virtually the same for many years, the processing equipment as well as design of the mills has continually been improved to increase production while reducing operating and maintenance costs. Also, considerable attention is paid to automatic sensing devices and automatic controls in order to assure maximum metallurgy and production at all times. For simplicity in this study most of these controls are not shown.Many of the porphyry copper deposits contain molybdenite and some also contain lead and zinc minerals.

Even though these minerals occur in relatively small amounts they can often be economically recovered as by-products for the expense of mining, crushing, and grinding is absorbed in recovery of the copper.

Because the copper in this type of ore usually assays only plus or minus 1% copper, the porphyry copper operations must be relatively large in order to be commercial. The flowsheet in this study illustrates a typical 3,000 ton per day operation. In general most operations of this type have two or more parallel grinding and flotation circuits. For additional capacity, additional parallel circuits are installed.

The crushing section consists of two or three crushing stages with the second or third stages in either closed or open circuit with vibrating screens. Generally, size of the primary crusher is not determined by capacity but by the basic size of the mine run rock. The mine-run ore is normally relatively large as most of the porphyry mines are open pit.The crushing section illustrated is designed to handle the full tonnage in approximately 8 to 16 hours thus having reserve capacity in case of expansion.

Many mills store not only the coarse ore but also the fine ore in open stockpiles using ore as the side walls and drawing the live ore from the center. During prolonged periods of crusher maintenance the ore walls can be bulldozed over the ore feeders to provide an uninterrupted supply of ore for milling.

As it is shown in this study the or 1 crushed ore is fed to a rod mill operating in open circuit and discharging a product approximately minus 14-mesh. The discharge from this primary rod mill is equally distributed to two ball mills which are in closed circuit with SRL Rubber Lined Pumps and two or more cyclone classifiers. The rod mill and two ball mills are approximately the same size for simplified maintenance.

Porphyry copper ores, usually medium to medium hard, require grinding to about 65-mesh to economically liberate the copper minerals from the gangue. Although a clean rougher tailing can often be achieved at 65-mesh the copper mineral is not liberated sufficiently to make a high grade copper concentrate, thus some form of regrinding is necessary on the rougher flotation copper concentrate. It is not unusual to grind the rougher flotation concentrate to minus 200-mesh for more complete liberation of mineral from the gangue.

The cyclone overflow from each ball mill goes to a Pulp Distributor which distributes the pulp to two or more parallel banks of Flotation Cells. These distributors are designed so that one or more flotation banks can be shut down for maintenance or inspection and still maintain equal distribution of feed to the remaining banks.

In some cases it is beneficial to have conditioning before flotation, but this varies from one operation to another and it is not shown in this flowsheet. Ten or more Free-Flow Flotation Cells are used per bank and these cells are divided into groups of four or six cells with an intermediate step-down weir between groups. Free-Flow Flotation Cells are specified, as metallurgy is extremely good while both maintenance and operating expenses are traditionally low. One or more Free-Flow Mechanisms can be stopped for inspection or even replaced for maintenance without shutting down the bank of cells.

The concentrates from rougher flotation cells are sent directly to regrind. Often the grind is 200-mesh. After regrind is flotation cleaning. In some cases the concentrate from the first three or four rougher flotation cells can be sent directly to cleaning without regrinding.

After the rougher flotation concentrate is reground it is cleaned twice in additional Free-Flow Flotation Machines with the recleaned concentrate going to final concentrate filtration or, as the metallurgy dictates, to a copper-moly separation circuit.

The thickening and filtering is similar to other milling operations, however, as the porphyry copper installations are often in arid areas, the mill tailing is usually sent to a large thickener for water reclamation and solids go to the tailings dam.

Automatic controls are usually provided throughout modern plants to measure and control pulp flow, pH and density at various points in the circuit. Feed and density controls are relatively common and the newer installations are using automatic pulp level controls on flotation machines and pump sumps. Automation is also being applied to the crushing systems.

The use of continuous on stream X-ray analysis for almost instantaneous metallurgical results is not shown in thus study but warrants careful study for both new and existing mills. Automatic sampling of all principal pulp flows are essential for reliable control.

The flowsheet in this study illustrates the modern approach to porphyry copper treatment throughout the industry. Each plant will through necessity have somewhat different arrangements or methods for accomplishing the same thing and reliable ore test data are used in most every case to plan the flowsheet and design the mill.

In most plants engaged in the flotation of ores containing copper-bearing sulphide minerals with or without pyrite, pine oil is employed as a frother with one of the xanthates or aerofloat reagents or a combination of two or more of them as the promoter. Lime is nearly always used for maintaining the alkalinity of the circuit and depressing any pyrite present. The reagent consumption is normally within the following limits

While good results are often obtained with ethyl xanthate alone as a promoter, the addition of a small quantity of one of the higher xanthates is frequently found to improve the recovery of those minerals that are not readily floated by the lower xanthate, especially those that are tarnished or oxidized, but since the action of a higher xanthate is, as a rule, more powerful than that of the ethyl compound, it is usually best to add no more of the former reagent than is necessary to bring up the less readily floatable minerals, controlling flotation with the less powerful and more selective lower xanthate. Better results are obtained with some ores by replacing the higher xanthate with one of the dithiophosphates, flotation being controlled, as before, with ethyl xanthate. Sometimes a dithiophosphate can be effectively used without the xanthate, although the dual promotion method is more common. A rule of thumb system for the selection of these reagents cannot be laid down as the character of the minerals differs so widely in different ores ; the best combination can only be found by experiment.When aerofloat is employed alone as the promoter, the reagent mixture is somewhat different from that given above. A reliable average consumption is difficult to determine as the plants working on these lines are few in number, but the following is what would normally be expected.If this combination of reagents gives results equal to those obtainable with a xanthate mixture, its employment has these advantages over the latter method: The control of flotation is not so delicate as with xanthates, it has less tendency to bring up pyrite, and, if selectivity is not required, the circuit may be neutral or only slightly alkaline.

When the ore is free from pyrite, the function of the lime, whatever the reagent mixture, is to precipitate dissolved salts and to maintain the alkalinity of the pulp at the value which has been found to givethe best results ; soda ash is seldom employed for this purpose. When pyrite is present, lime performs the additional function of a depressor, the amount used being balanced against that of the promoterthat is, no more lime should be added than is required to prevent the bulk of the pyrite from floating, as any excess tends to depress the copper minerals, and no more of the promoter should be employed than is needed to give a profitable recovery of the valuable minerals in a concentrate of the desired grade, since any excess tends to bring up pyrite. In many cases a more effective method of depressing pyrite is to add a small quantity of sodium cyanidee.g., 0.05-0.10 lb. per tonin conjunction with lime, less of the latter reagent then being necessary than if it were used alone.

It is not often that a conditioning tank has to be installed ahead of the flotation section in the treatment of sulphide copper ores, as the grinding circuit usually provides suitable points for the introduction of the reagents. The normal practice is to put lime into the primary ball mills and to add xanthates at the last possible moment before flotation, while aerofloat and di-thio-phosphates are preferably introduced at some point in the grinding circuit, since they generally need an appreciable time of contact as compared with xanthates. There is no special place for the addition of pine oil, but care should be taken if it is put into the primary ball mills, as a slight excess may cause an undue amount of froth to form in the classifiers.

In a plant where the primary slime is by-passed round the grinding circuit, it is necessary to ensure that this portion of the pulp receives its correct proportion of and contact time with the reagents.

As regards flotation installations, the present tendency is to employ machines of the air-lift or Callow-Maclntosh rather than of the subaeration type. While two stages of cleaning (circuits 10 and 11) are sometimes essential to the production of a clean final concentrate, circuits 8 and 9 comprising a single stage of cleaning are probably the most widely used. Occasionally the primary machines can be run as rougher-cleaner cells (circuit No. 5), particularly when they are of the air-lift or subaeration type. This method, however, is not often employed, although its use is more common in the flotation of copper sulphide minerals than of any other class of ore ; a stage of cleaning is preferable as providing greater lattitude of control.

Two variations of normal procedure are worth notice. In one or two plants employing two-stage grinding, improved results have been obtained by separating the slime from the primary ball mill circuit and sending it direct to a special flotation section. This method is useful when the feed to the flotation plant contains an appreciable quantity of fines, which, due generally to oxidation through exposure, require different treatment from the unweathered part of the ore. Such fines are usuallyfriable and can be separated as slime from the primary grinding circuit without the inclusion of an undue proportion of unoxidized material, the bulk of which thus passes to the secondary grinding circuit and thence to its own division of the flotation plant.

The second variation consists of grinding the rougher concentrate before cleaning. The method is applicable to an ore in which the copper- bearing minerals are so intimately associated with pyrite that very fine grinding is necessary to liberate them completely. It is often possible, after grinding such an ore to a comparatively coarse mesh, to make a profitable recovery of the copper in a low-grade concentrate which does not represent too large a proportion, say 30% or less, of the total weightof the feed. The concentrate can then be reground and refloated with the production of a high-grade copper concentrate together with a low- grade pyritic tailing suitable for return to the roughing circuit. This method is likely to be less costly than one involving the fine grinding of the whole ore. No standard system can be given for handling the various products as their disposal depends so much on the occurrence of the minerals and the efficiency of the regrinding operations, but a typical flow sheet is illustrated in circuit No. 12 (Fig. 60). It is diagrammatic to the extent that the thickener and regrinding unit may receive its feed from several roughing machines and deliver its discharge to a number of cleaning cells. It is usual to dewater the rougher concentrate and return the water to the primary circuit for two reasons : First, to supply the regrinding mill with a thick enough pulp for efficient operation, and, secondly, as far as possible to prevent the reagents used in the roughing circuit from entering the cleaning section.

In normal practice a recovery of over 90% of the copper which is present as a sulphide is generally possible, whatever the flotation process or circuit employed. As regards the average grade of concentrate, no more can be said than that it depends on the class of the copper-bearing minerals present and their mode of occurrence and on the character of the gangue. It usually contains over 20% of copper, but a difficult chalcopyritic ore may yield a concentrate with less than that percentage, while it is theoretically possible to obtain one running over 75% should the mineral consist entirely of pure chalcocite.

The flotation of native copper ores is nearly always preceded by gravity concentration in jigs and tables not only because the combined process is more economical as regards costs, but also because the copper often occurs as large grains which flatten out during grinding and cannot be broken to a size small enough for flotation. The flow sheet depends on the mode of occurrence of the mineral. The tailings from some of the gravity concentration machines may be low enough in value to be discarded, but those products which still contain too much copper to be sent to waste are thickened and reground, should either operation be necessary, and then floated with pine oil and a xanthate or aerofloat reagent in a neutral or slightly alkaline circuit. The reagent consumption is approximately the same as that given for the treatment of copper- bearing sulphides. While a pine oil, lime, and ethyl xanthate mixture has proved satisfactory, better results have sometimes been obtained by the substitution of aerofloat and sodium di-ethyl-di-thio-phosphate, soda ash being used instead of lime on account of its gangue deflocculating properties. On the average 0-12 lb. per ton of aerofloat and 0.03 lb. of the di-thio-phosphate are substituted for 0.1 lb. of xanthate.

Since a high-grade concentrate is desired in order to keep smelting costs as low as possible, the circuit usually comprises two stages of cleaning. In most plants flotation is carried out in mechanically agitated machines.

The problem of the flotation of oxidized copper ores has not yet been solved. One or two special processes are in operation for the flotation of malachite and azurite, but none of them has more than a limited application; nor has any method been worked out on a large scale for the bulk flotation of mixed oxidized and sulphide copper minerals when the former are present in the ore in appreciable quantity.

copper sulfide flotation

Copper, due to the present world demand and price, is of foremost interest to the mining industry. Many new properties are either in the process of being brought into production or are being given consideration. Copper minerals usually occur in low grade deposits and require concentration prior to smelting. The method and degree of concentration depends on smelter location and schedules, together with the nature of the ore deposit. Sulphide copper ores generally occur with pyrite, pyrrhotite, arsenopyrite and molybdenite, and with gold and silver. A complete copper-iron separation may not always be essential for the maximum economic recovery and often is tied to the distribution of the gold and silver values.

The above flowsheet is designed for the treatment by flotation of copper as chalcopyrite with gold and silver values. The ore, ranging from 60-65% silica, with pyrite, arsenopyrite, and calcite with 3 to 4% copper. This flowsheet, though simple, is adequate for tonnages of 100 to 500 tons or more per day, depending on the size of equipment selected. It can be readily expanded by duplicating units for increased tonnages. By minor circuit changes, it provides the flexibility to treat a range of ore conditions which are often encountered in any mining operation. Generally in these small plants the recovery of molybdenum is disregarded unless it is present in considerable amounts. Larger plants generally will incorporate a circuit for molybdenum recovery from the copper concentrate by flotation. Sub- A Flotation is standard for this service.

Crushing Section. The crushing section with two-stage reduction is suitable for smaller tonnages, depending on the ore characteristics. Three-stage reduction in either an open or closed circuit, with screens for the removal of fines can be employed where conditions warrant. The fines are removed by a grizzly or screen ahead of each reduction stage for higher efficiency and for reduced wear on crushing surfaces.

Feed control is essential to efficient grinding and helps reduce surges and fluctuations throughout the entire plant. The Ball Mill in closed circuit with a Spiral Classifier discharges the pulp at about 60% minus 200 mesh. The Ball Mill is equipped with a Spiral Screen on the discharge for removal of any tramp oversize, worn grinding balls, and wood chips from the circuit.

The pulp from the Conditioner is treated in a 10-cell Sub-A Flotation Machine and a 4-cell Sub-A Flotation machine. Sometimes conditioners are not provided; however, their use insures that reagents are thoroughly mixed into the pulp ahead of flotation. This gives a more uniform feed and effective use of reagents plus improved flotation conditions. The 10-cell Sub-A Flotation Machine is of the free-flow type. Weirs for the control of pulp level through the machine are provided at the fourth, eighth and tenth cells. This free-flow type provides ample volume for normal fluctuations in the feed rate without cell level adjustment. Sand relief ports help extend the long life of the molded rubber wearing parts.

The first eight cells produce a rougher concentrate while the last two cells act as scavengers. The concentrate or middling product from these two cells is returned by gravity back to the fifth cell. The rougher concentrate from the first eight cells is cleaned in two stages in the four-cell standard Sub-A Flotation Machine, of the cell-to-cell type. No pumps are needed for the return of these flotation products for cleaning. This feature in Sub-A Flotation Machines gives added flexibility by enabling the operator to change cleaning circuits readily, should conditions require. The tailings from the cleaner flotation section are pumped back to the ball mill for regrind. To control dilution a cone classifier is placed in this circuit with the coarse solids going to regrind and the overflow used as dilution in the mill and classifier. It is possible to eliminate this classification in some cases but control is less positive. A separate regrind section could be provided if the quantity of middling products were enough to make this section feasible.

The final cleaned flotation concentrate flows or is pumped to a Spiral Rake Thickener. A Adjustable Stroke Diaphragm Pump, mounted on the thickener superstructure, meters the thickened concentrate to the Disc Filter. The Thickeners are often used to store concentrates for filtration at fixed intervals. These units have heavy duty construction throughout, overload indicators and positive rake lifting features. The Diaphragm Pump is used for concentrate recirculation purposes during such periods.

Lime is added to the Ball Mill by a Cone Type Dry Reagent Feeder. Other reagents, such as cyanide, xanthate, and a frother are fed and controlled by No. 12A Wet Reagent Feeders to the classifier and to the conditioner ahead of flotation.

This flowsheet stresses simplicity without sacrifice of efficiency. The factors of flexibility are essential to meet changing ore and market conditions. The unit arrangement which can be expanded by sections for increased capacity is an important feature. The equipment indicated has been proven for long life and low maintenance, and to give superior results. The Sub-A Flotation Machines are designed for high capacity and with features of flexibility to handle fluctuating conditions with a minimum of operating attention. Low final tailings and high grade concentrate are assured through the selective action of the Sub-A in the roughing, cleaning, and recleaning circuits.

Large scale mining operations, of which the porphyry coppers are typical, must resort to concentration. This is necessary as the ores are generally low grade and require flotation to produce a concentrate acceptable to the smelters.

These large scale milling operations handling low grade ore must provide very careful planning in the design of their plant flowsheet and selection of equipment. Milling circuits must be as simple as possible and for large tonnages, as few as possible. It is for this reason grinding mills and flotation circuits arenow designed to handle these large tonnages at low cost.

Sub-A Flotation Machines are a basic part of large tonnage operations and their use assures maximum economic recovery. Particular emphasis has been placed on the design and operation of these machines for roughing, scavenging and cleaning. Mechanisms have been greatly simplified and molded rubber wearing parts are standard for maximum abrasion resistance.

Three stage crushing is illustrated in the flowsheet; however, it is possible and practical to eliminate the third stage by incorporating a rod mill in the grinding section. This is a very practical arrangement and often a necessity when handling wet, sticky ore. There is evidence that this combination of crushing and grinding results in lower costs for reducing large tonnages of ore to flotation size.

The flowsheet illustrates a typical grinding circuit with a rod mill in open circuit. Its discharge, usually all 14 mesh, goes to a classifier for removal of finished material. The classifier sands are ground in a ball mill in closed circuit with the same classifier. High speed rod milling with speeds up to 80% of critical has shown definite improvement in efficiency and grinding capacity. Proper selection of mill density and grinding charges are also factors of importance. Usually the rod mill is operated at lower density so it acts partially as its own classifier for retaining oversize for further size reduction.

Some conditioning of the pulp ahead of flotation is usually very beneficial and will result in more uniform and rapid flotation of a selective high grade concentrate. For this service the (patented) Super Agitator and Conditioner is standard. Reagents added at this point are thoroughly mixed and reacted with the pulp. Any tendency of the pulp to froth prematurely is readily overcome by the patented standpipe arrangement which also assures positive pulp circulation.

For large tonnage circuits normally encountered in many of the copper operations the open or free flow type Sub-A Super Rougher Flotation Machine is recommended. Intermediate cell weirs are eliminated and circulation of pulp through the impeller is fixed to provide the desired agitation and aeration for rougher flotation conditions. Machines are usually arranged with up to six cells being open or free-flow without intermediate weirs. Two or more machines are always provided in series. This allows adequate volume for absorbing surges and fluctuation in feed without cell adjustment. Mineral and middlings in the teeter or quiescent zone of the cell are gradually forced upward to the froth removal zone. Only the coarser material in the agitation zone passes through the impeller for further conditioning and bubble attachment.

In the flowsheet each circuit consists of 16 or 18 cells in 4 or 6 cell units. These Sub-A Super Rougher Flotation Free-Flow Machines are in series. All of the mechanisms are of the single impeller type and are completely supported from the superstructure to facilitate maintenance. All heavy hoods and castings are eliminated and the impeller-diffuser clearance is pre-set and accurately maintained throughout the long life of the heavy duty moulded rubber wearing parts. The last two cells are the super scavenger type giving veryintense agitation and aeration to float the last trace of recoverable mineral or middling for re-treatment.

Rougher flotation concentrates are cleaned in a standard Sub-A Flotation Machine with cell to cell pulp level control. This arrangement for upgrading concentrates is universal in its acceptance by the ore dressing industry. Two or more stages of cleaning in the same machine are accomplished without auxiliary pumps and ideal flotation conditions for producing high-grade concentrates are easily maintained.

Cleaner flotation tailings are returned to the head of the rougher flotation circuit for retreatment. In many milling circuits, particularly if coarse grinding is used, the cleaner tailings will contain middlings or mineral with attached particles of gangue. In these cases it is necessary to thicken or classify and regrind this fraction. Centrifugal classifiers are being very successfully applied for the classification step although they do take considerable power and require more maintenance than a thickener with its underflow going to a regrind circuit.

The flowsheet incorporates thickening for both the concentrates and tailings for water reclamation and tailings disposal purposes. A Adjustable Stroke Diaphragm Pump on the concentrate thickener assures absolute control of the volumes delivered to the Disc Filter. When the filter is down temporarily for bag changes the concentrates may be recirculated to the thickener by this same pulp.

Flexibility and simplicity are the two most important points to design into any large tonnage flotation operation. The arrangement shown is flexible and will permit addition of extra milling sections up to the limit of the designed capacity of the crushing plant. Sub-A Flotation Machines are designed specifically for high tonnage installations and have been proven for all types of applications. Rugged construction will give years of service at lowest possible cost. This flowsheet is readily adaptable for the treatment of other ores. Note particularly the location and use of Automatic Sampler.

Copper, one of our most important minerals, is found in many parts of the world. One of the major sources of Copper is the so-called porphyry ores such as the large deposits in the west and southwestern United States, Mexico, South America and Europe.

Porphyry ores, with copper occurring in the form of Chalcocite and Chalcopyrite are normally low in grade and the copper minerals must be concentrated before smelting. In this flowsheet using Sub-A Cells the emphasis is on maximum economic recoveryhigh concentrating efficiency together with a premium smelter feed with a low alumina and magnesia content in the flotation concentrate.

To obtain lowest tailings from this ore usually requires scavenging of rougher flotation tails. This is performed ideally by the Sub-A Super Rougher Flotation Machine which was specially developed for this duty. This machine has a double impeller and gives tremendous aeration. The flowsheet in this study is designed to get the maximum recovery from a large tonnage of porphyry copper ore.

The crushing section consists of three-stage ore reduction with either a grizzly or vibrating screen between each crushing stage. Removing fines before putting the ore through a crusher increases the efficiency of the crusher as it is then only working on material that must be reduced, and is not hampered by fines already reduced in size. Electromagnets and magnetic pulleys are used to remove tramp iron from the ore, the former to remove the iron near the surface and the magnetic pulley to remove the tramp iron close to the conveyor belt.

Porphyry copper ores usually are medium to medium hard and require grinding to about 65 mesh to economically liberate the copper minerals from the siliceous gangue. Sometimes a regrinding circuit is advantageous on the rougher concentrate and on the scavenger concentrate. This will liberate the mineral from the middling products and increase the recovery by putting those mineral particles into the concentrate. Rougher flotation may be accomplished at a relatively coarse grind and the subsequent regrind performed on a comparatively small tonnage.

Lime is usually added to the ball mill feed by a Dry Reagent Feeder. The frother and promoter are added in the classifier prior to flotation to realize the full effect of the reagent. Reagents can also be stage- added to the cells in the flotation circuit.

Standard Sub-A Flotation Machines are used for both the rougher and cleaner circuits, where their cell-to-cell principle gives both high recovery and a good grade of concentrate. The rougher concentration is accomplished in 6 or 8-cell flotation machines, with the concentrate from each goingto a separate bank for cleaning and re-cleaning. No. 30 Sub-A Flotation Machines are ideal for large tonnage operations, as each bank will handle from 1000 tons upward per day. Tails from the rougher circuit go to a scavenger circuit. Roughing, scavenging, cleaning and recleaning can be carried out in one bank of Sub-As. This is possible because of the distinctive gravity return of a product from any cell to any other cell of a bank without using pumps. In large installations, however, these steps are usually carried out in separate banks of cells. The scavenger flotation circuit consists of a 4-cell, Sub-A Super Rougher Flotation Machine with its super aeration. The concentrate from scavenger cells is returned to the head of the rougher cells and tails are sent to tailing pond. The new Sub-A Super Rougher Machine is designed especially to produce the lowest possible tailings in the mill circuit by scavenging off the last bit of recoverable and often difficult to float mineral. The Automatic Sampler is used on the flotation feed, concentrates and tailings to establish close mill control.

The flowsheet incorporates a thickener on the copper concentrates to thicken for optimum filtering. This also serves as a temporary storage space to accommodate operating requirements. The Adjustable-Stroke Diaphragm Pump on the thickener gives absolute control of volumes pumped to the filter. When the filter is shut down concentrates may be recirculated to the thickener by this same pump.

It is essential to have flexibility in any mill circuit, but particularly in large-tonnage operations such as this. Changing ore, changing market conditions and many other factors make this flexibility absolutely necessary. A slight change, easily made, in a flexible flowsheet may increase tonnage, improve recovery and lower grinding and reagent costs.

investigation into the flotation of malachite, calcite and quartz with three phosphate surfactants - sciencedirect

The flotation response of malachite, calcite and quartz to bis (2-ethylhexyl) phosphate (DEHPA), dibutyl phosphate (DBP) and tributyl phosphate (TBP) was evaluated by micro-flotation experiments. The results showed that DEHPA exhibited an impressive flotation selectivity for malachite against calcite/quartz in the pH range of 6.09.0 and achieved superior malachite flotation recovery over DBP and TBP. The flotation mechanism of DEHPA to malachite was farther investigated through adsorption, contact angle, zeta potential, Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The findings inferred that DEHPA reacted with the surface copper atom of malachite via its O atoms of POH and PO to form the hydrophobic surface complexes of Cu(II)-DEHPA. The double active center of the P(O)OH group might be contributed to the stronger affinity of DEHPA and DBP to malachite than that of TBP with the single active center of the PO group. TBP returned the lowest malachite recovery among the three phosphate surfactants, even it has more hydrophobic-carbon atoms than those of DBP.

minerals | free full-text | a new collector for effectively increasing recovery in copper oxide ore-staged flotation | html

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Feature Papers represent the most advanced research with significant potential for high impact in the field. Feature Papers are submitted upon individual invitation or recommendation by the scientific editors and undergo peer review prior to publication.

The Feature Paper can be either an original research article, a substantial novel research study that often involves several techniques or approaches, or a comprehensive review paper with concise and precise updates on the latest progress in the field that systematically reviews the most exciting advances in scientific literature. This type of paper provides an outlook on future directions of research or possible applications.

Editors Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to authors, or important in this field. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

henan mining machinery and equipment manufacturer - flotation cell in mineral copper file type pdf

... concentrate, the pure mineral flotation and solution ... We present an approach to model the dynamic of a copper flotation process. ..... This file collect the ...froth flotation copper ... Flotation Cell, Flotation Cell Products, ... Vintech Ltd supplies a variety of reagents for beneficiation of different types of mineral ores.

Ore beneficiation equipment, sand making equipment, crushing equipment and powder grinding equipment, which are widely used in various industries such as metallurgy, mine, chemistry, building material, coal, refractory and ceramics.

a novel decyl-salicyl hydroxamic acid flotation collector: its synthesis and flotation separation of malachite against quartz - sciencedirect

DSHA was firstly introduced in malachite flotation.DSHA adsorbed on malachite surfaces through co-adsorption mode.DSHA showed powerful collecting ability to malachite and satisfied selectivity against quartz.Mixed collectors of DSHA and sodium isobutyl xanthate achieved higher selective separation of copper oxide ore.

In this study, a novel decyl-salicyl hydroxamic acid (DSHA) collector was synthesized and applied to a malachite flotation. Subsequently, its flotation performance on malachite was studied through micro- and batch-flotation tests, as well as through zeta-potential and X-ray photoelectron spectroscopy (XPS) analyses. The results of micro-flotation tests indicate that DSHA exhibits a powerful ability to collect malachite and a satisfactory selectivity against quartz. The batch-flotation tests also prove that DSHA is an effective collector for copper oxide ore. Furthermore, mixed collectors of DSHA and sodium isobutyl xanthate (SIBX) achieved a better selective separation of CuO than individual DSHA, SIBX, or salicyl hydroxamic acid (SHA). The results of a zeta-potential analysis infers that DSHA may chemisorb on malachite.The XPS analysis results provide clear evidence that DSHA adsorbs on malachite through the co-adsorption mode.

minerals | free full-text | a new collector for effectively increasing recovery in copper oxide ore-staged flotation

All articles published by MDPI are made immediately available worldwide under an open access license. No special permission is required to reuse all or part of the article published by MDPI, including figures and tables. For articles published under an open access Creative Common CC BY license, any part of the article may be reused without permission provided that the original article is clearly cited.

Feature Papers represent the most advanced research with significant potential for high impact in the field. Feature Papers are submitted upon individual invitation or recommendation by the scientific editors and undergo peer review prior to publication.

The Feature Paper can be either an original research article, a substantial novel research study that often involves several techniques or approaches, or a comprehensive review paper with concise and precise updates on the latest progress in the field that systematically reviews the most exciting advances in scientific literature. This type of paper provides an outlook on future directions of research or possible applications.

Editors Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to authors, or important in this field. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

Zhu, Renfeng, Guohua Gu, Zhixiang Chen, Yanhong Wang, and Siyu Song. 2019. "A New Collector for Effectively Increasing Recovery in Copper Oxide Ore-Staged Flotation" Minerals 9, no. 10: 595.